Synthesis and structural features of Co(II) compounds with 3-arylidene-1-pyrroline derivatives and monocarboxylic acids anions

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

A series of acetate and trifluoroacetate compounds of cobalt(II) with derivatives of 3-arylidene-1-pyrrolines (X-L; X = Cl, OH) as N-donor ligands was synthesized. Varying the synthesis and crystallization conditions made it possible to obtain coordination compounds of various compositions and structures: a tetranuclear complex based on a cubane fragment {Co4(OH)4}4– — [Co4(OH)4(Cl–L)4(OAc)4] (I), a 1D-polymer complex [Co(H2O)(Cl–L)2(CF3COO)1.167(OAc)0.833]n (II) or a molecular complex [Co(OH–L)2(OAc)2] (III). The synthesized compounds were characterized by X-ray diffraction, IR spectroscopy and CHN analysis. The structure and crystal packing of the obtained complexes were analyzed in detail, the main structure-forming non-covalent interactions in crystals were identified.

About the authors

Yu. K. Voronina

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: juliavoronina@mail.ru
Moscow, Russia

O. V. Zvereva

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Email: juliavoronina@mail.ru
Moscow, Russia; Moscow, Russia

M. A. Shmelev

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: juliavoronina@mail.ru
Moscow, Russia

E. N. Zorina-Tikhonova

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: juliavoronina@mail.ru
Moscow, Russia

A. V. Rogachev

MIREA — Russian Technological University

Email: juliavoronina@mail.ru
Moscow, Russia

A. A. Sidorov

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: juliavoronina@mail.ru
Moscow, Russia

I. L. Eremenko

N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Email: juliavoronina@mail.ru
Moscow, Russia

References

  1. Keller L.-A., Merkel O., Popp A. // Drug Deliv Transl Res. 2022. V. 12. № 4. P. 735.
  2. Jeong W.Y., Kwon M., Eun Choi H., Su Kim K. // Biomater Res. 2021. V. 25. № 1. P. 24.
  3. Thomford N.E., Senthebane D.A., Rowe A. et al. // Int. J. Mol. Sci. 2018. V. 19. № 6. Р. 1578.
  4. Krasnovskaya O., Naumov A., Guk D. et al. // Int. J. Mol. Sci. 2020. V. 21. № 11. Р. 3965.
  5. Psomas G. // Coord. Chem. Rev. 2020. V. 412. P. 213259.
  6. Ghanghas P., Choudhary A., Kumar D., Poonia K. // Inorg. Chem. Commun. 2021. V. 130. P. 108710.
  7. El-Gammal O.A., Mohamed F.S., Rezk G.N., El- Bindary A.A. // J. Mol. Liq. 2021. V. 330. P. 115522.
  8. Pellei M., Del Bello F., Porchia M., Santini C. // Coord. Chem. Rev. 2021. V. 445. P. 214088.
  9. Uvarova M.A., Lutsenko I.A., Shmelev M.A. et al // New. J. Chem. 2024. V. 48. № 2. P. 717.
  10. Shmelev M.A., Chistyakov A.S., Razgonyaeva G.A. et al. // Crystals. 2022. V. 12. № 4. Р. 508.
  11. Leung C.-H., Zhong H.-J., Chan D. S.-H. et al. // Coord. Chem. Rev. 2013. V. 257. № 11‒12. P. 1764.
  12. Ronconi L., Sadler P.J. // Coord. Chem. Rev. 2007. V. 251. № 13‒14. P. 1633.
  13. Liu W., Gust R. // Coord. Chem. Rev. 2016. V. 329. P. 191.
  14. Bazhina E.S., Bovkunova A.A., Shmelev M.A. et al. // Inorg. Chim. Acta. 2023. V. 547. Р. 121359.
  15. Klintworth R., de Koning C.B., Opatz T., Michael J.P. // J. Org. Chem. 2019. V. 84. № 17. P. 11025.
  16. Saraswat P., Jeyabalan G., Hassan M.Z. et al. // Synth. Commun. 2016. P. 1643.
  17. Ahmad Bhat A., Singh I., Tandon N., Tandon R. // Eur. J. Med. Chem. 2023. V. 246. P. 114954.
  18. Fernandes L. de P., Silva J.M.B., Martins D.O.S. et al. // Int. J. Mol. Sci. 2020. V. 21. № 21. P. 8355.
  19. Delehanty J.B., Bongard J.E., Thach D.C. et al. // J. Biol. Chem. 2008. V. 16. № 2. P. 830.
  20. Smolobochkin, A.V., Gazizov, A.S., Melyashova, A.S. et al. // RSC Advances. 2017. V. 7. № 80. P. 50955.
  21. Rizbayeva T.S., Smolobochkin A.V, Gazizov A.S. et al. // J. Org. Chem. 2023. V. 88. P. 11855.
  22. Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
  23. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Cryst. 2009. V. 42. P. 339.
  24. Casanova D., Llunell M., Alemany P., Alvarez S. et al. // Chem. Eur. J. 2005. V. 11. P. 1479.
  25. Lee S.Y., Kim N., Lee M.M. et al. // Dalton Trans. 2016. V. 45. P. 1727.
  26. Nguyen A.I., Wang J., Levine D.S. et al. // Chem. Sci. 2017. V. 8. P. 4274.
  27. Zhao H., Bacsa J., Dunbar K.R. // Acta Crystallogr. E. 2004. V. 60. P. m637.
  28. Fomina I.G., Dobrokhotova Zh.V, Aleksandrov G.G. et al. // Russ. Chem. Bull. 2009. V. 58. P. 11.
  29. Newton G.N., Cooper G.J.T., Kögerler P. et al. // J. Am. Chem. Soc. 2008. V. 130. P. 790.
  30. Cooper G.J.T., Newton G.N., Kogerler P. et al. // Angew. Chem. Int. Ed. 2007. V. 46. P. 1340.
  31. Andaloussi Y.H., Sensharma D., Bezrukov A.A et al. // Cryst. Growth. Des. 2023. V. 23. P. 3019. https://doi.org/10.1021/acs.cgd.3c00094
  32. Zvereva O.V., Rizbaeva T.S., Shmelev M.A. et al. // J. Struct. Chem. 2024. V. 65. № 7. P. 1439.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2025 Russian Academy of Sciences

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).