Control Over the Reactivity of Aggregates and Mineral Additives in Portland Cement Compositions by Electron Beam and Heat Treatment

A. S. Brykov; Брыков А. С.; S. V. Myakin; Мякин С. В.; M. M. Sychev; Сычев М. М.

doi:10.31857/S0132665121100279

Control Over the Reactivity of Aggregates and Mineral Additives in Portland Cement Compositions by Electron Beam and Heat Treatment

作者: Brykov A.S.¹, Myakin S.V.¹, Sychev M.M.¹^,2
隶属关系:
1. St. Petersburg State Technological Institute (Technical University)
2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences
期: 卷 49, 编号 1 (2023)
页面: 107-114
栏目: Articles
URL: https://journal-vniispk.ru/0132-6651/article/view/139322
DOI: https://doi.org/10.31857/S0132665121100279
EDN: https://elibrary.ru/CETVGJ
ID: 139322

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详细

The effect of electron-beam treatment (EBT) and heat treatment (HT) of silica-based aggregates and mineral additives in Portland cement mortars on the intensity of alkali-silica reactions (ASRs) with their participation, which are dangerous for concrete structures, is studied. It is established that heating to a temperature of 900°C and the EBT of sand free of alkali-reactive inclusions, leads to a significant increase in the reactivity of cement-sand mortar mixtures, which increases with an increase in the absorbed dose and a corresponding increase in the content of acid hydroxyl groups on the sand surface. In the case of sand containing reactive inclusions of chalcedony, EBT leads to an increase in reactivity, and HT, to a decrease. Treatment of microsilica and metakaolin mineral additives capable of ASR inhibition leads to an increase in their inhibitory effect. The results obtained are promising for modeling the expansion of concrete as a result of ASR and increasing their resistance to fracture in alkaline media.

关键词

Portland cement, alkali-silica reactions, pozzolanic additives, chalcedony, metakaolin, electron beam processing, heat treatment, surface, functional groups

参考

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