Formation of the Structure and Phase Composition of Polycrystalline Diamond with Cobalt Infiltration in the System Diamond – Hard Alloy


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Abstract

Polycrystalline diamond composites (PCD) were obtained by cobalt infiltration from a hard-alloy substrate into a porous diamond layer at temperature 1600°C and pressure 6.0 GPa in a cubic hydrostatic-compression press. To improve the thermal stability of the composite the upper layer of the cobalt was etched by hydrofluoric acid to depth 150 μm. Transmission electron microscopy (TEM) was used to analyze the interaction at grain-binder and grain-grain boundaries. After cobalt infiltration a nanodiamond phase and a cubic cobalt-carbide phase CoCx are present on the grain-binder intergrain boundaries while after etching of the cobalt bulbous structures were found in the surface layer of the sintered polycrystalline diamond composite.

About the authors

A. S. Anokhin

A. A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences (IMET RAN)

Author for correspondence.
Email: aanokhin@imet.ac.ru
Russian Federation, Moscow

S. S. Strel’nikova

A. A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences (IMET RAN)

Email: aanokhin@imet.ac.ru
Russian Federation, Moscow

M. A. Andrianov

Mikrobor Kompozit JSC

Email: aanokhin@imet.ac.ru
Russian Federation, Moscow

V. V. Tkachenko

Mikrobor Kompozit JSC

Email: aanokhin@imet.ac.ru
Russian Federation, Moscow

A. N. Shipkov

Mikrobor Kompozit JSC

Email: aanokhin@imet.ac.ru
Russian Federation, Moscow

E. V. Kukueva

National Research Center Kurchatov Institute

Email: aanokhin@imet.ac.ru
Russian Federation, Moscow

A. E. Gol’dt

Skolkovo Institute of Science and Technology (Skoltekh)

Email: aanokhin@imet.ac.ru
Russian Federation, Moscow

O. T. Zaremba

Skolkovo Institute of Science and Technology (Skoltekh)

Email: aanokhin@imet.ac.ru
Russian Federation, Moscow

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