Magnetic nanoparticles Fe 3 O 4  modified with sodium dodecyl sulphate for removing methylene blue from water

K. E. Magomedov; Магомедов К. Э.; A. S. Omelyanchik; Омельянчик А. С.; S. A. Vorontsov; Воронцов С. А.; E. Čižmár; Чижмар Э.; V. V. Rodionova; Родионова В. В.; E. V. Levada; Левада Е. В.

doi:10.31857/S0367676523701429

Magnetic nanoparticles Fe₃O₄ modified with sodium dodecyl sulphate for removing methylene blue from water

Authors: Magomedov K.E.¹^,2, Omelyanchik A.S.¹, Vorontsov S.A.¹, Čižmár E.³, Rodionova V.V.¹, Levada E.V.¹
Affiliations:
1. Immanuel Kant Baltic Federal University
2. Dagestan State University
3. Institute of Physics, Faculty of Science, P.J. Šafárik University
Issue: Vol 87, No 6 (2023)
Pages: 819-827
Section: Articles
URL: https://journal-vniispk.ru/0367-6765/article/view/135403
DOI: https://doi.org/10.31857/S0367676523701429
EDN: https://elibrary.ru/VLIVDS
ID: 135403

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Abstract

We show that surface-modified magnetic iron oxide nanoparticles with an average size of about 10 nm have a high adsorption capacity for sorption of pollutants from wastewater. A significant advantage of using magnetic materials is the ability to extract the sorbent using an external magnetic field, which makes the purification process more efficient. We found that the anionic substance sodium dodecyl sulfate increases the electrostatic attraction to the cationic compound methylene blue, and also prevents the aggregation of nanoparticles, thus increasing the active surface. The sorption capacity of magnetic nanoparticles after surface functionalization increased by a factor of 250 compared to unmodified iron oxide nanoparticles. The mechanism and kinetic parameters of the sorption process were determined, as well as the optimal conditions for increasing the efficiency of the sorption process.

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