A novel method for the preparation of nanosized tysonite phases

R. M. Zakalyukin; Закалюкин Р. М.; E. A. Levkevich; Левкевич Е. А.; V. V. Grebenev; Гребенев В. В.; T. Yu. Glazunova; Глазунова Т. Ю.; М. E. Buzoverov; Бузоверов М. Е.; A. S. Kumskov; Кумсков А. С.

doi:10.31857/S0367676523702411

A novel method for the preparation of nanosized tysonite phases

Authors: Zakalyukin R.M.¹^,2, Levkevich E.A.¹^,2, Grebenev V.V.¹, Glazunova T.Y.³, Buzoverov М.E.³, Kumskov A.S.¹
Affiliations:
1. Shubnikov Institute of Crystallography of Federal Scientific Research Centre “Crystallography and Photonics” of the Russian Academy of Sciences
2. MIREA – Russian Technological University
3. Moscow State University, Faculty of Chemistry
Issue: Vol 87, No 10 (2023)
Pages: 1381-1384
Section: Articles
URL: https://journal-vniispk.ru/0367-6765/article/view/141830
DOI: https://doi.org/10.31857/S0367676523702411
EDN: https://elibrary.ru/WXFFZT
ID: 141830

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Nanopowders of tysonite solid solutions La_{1 –} _xBa_xF_{3 –} _x (х = 0–0.07) were synthesized for the first time by thermal decomposition of lanthanum and barium trifluoroacetates. The samples obtained were characterized by electron microscopy, X-ray phase analysis, and impedance spectroscopy. Nanoparticles are crystalline and have characteristic sizes of 20–75 nm. The ionic conductivity of solid solutions in the range up to 300°C is determined by surface phenomena at the particle boundaries.

References

Закалюкин Р.М., Болталин А.И., Федоров П.П. и др. // Физ. и хим. стекла. 1999. Т. 25. № 3. С. 355.
Сорокин Н.И., Закалюкин Р.М., Глазунова Т.Ю. и др. // Неорг. матер. 2000. Т. 36. № 8. С. 1008.
Dhanapala D.B., Munasinghe H.N., Suescun L. et al. // Inorg. Chem. 2017. V. 56. P. 13311.
Zakalyukin R.M., Levkevich E.A., Kumskov A.S. // Ceram. Int. 2022. V. 48. No. 18. P. 26565.
Nowroozi M.A., Mohammad I., Molaiyan P. et al. // J. Mater. Chem. A. 2021. V. 9. No. 10. P. 5980.
Toma O., Rotella H., Dahab H. et al. // J. Alloys Compounds. 2021. V. 862. Art. No. 158683.
Gopinadh S.V., Phanendra P.V.R.L., John B. et al. // Sust. Mater. Technol. 2022. V. 32. Art. No. e00436.
Buchinskaya I.I., Karimov D.N., Sorokin N.I. // Crystals. 2021. V. 11. No. 6. P. 629.
Astruc A., Cochon C., Dessourses C. et al. // Appl. Catalysis A. 2013. V. 453. P. 20.
Astruc A., Celerier S., Pavon E. et al. // Appl. Catalysis B. 2017. V. 204. P. 107.
Кузнецов С.В., Федоров П.П., Воронов В.В. и др. // Журн. неорг. хим. 2010. Т. 55. № 4. С. 536; Kuznetsov S.V., Fedorov P.P., Voronov V.V. et al. // Russ. J. Inorg. Chem. 2010. V. 55. No. 4. P. 484.
Chen X., Wu Y. // J. Alloys Compounds. 2020. V. 817. Art. No. 153075.
He W., Du H., Fu J. et al. // New J. Chem. 2021. V. 45. P. 1446.
Закалюкин Р.М., Левкевич Е.А., Николаева А.В.// Тонкие хим. технол. 2021. Т. 16. № 5. С. 426; Zakalyukin R.M., Levkevich E.A., Nikolaeva A.V. // Fine Chem. Tech. 2021. V. 16. No. 5. P. 426.
Chable J., Dieudonne B., Body M. et al. // Dalton Trans. 2015. V. 44. P. 19625.
Chable J., Martin A.G., Bourdin A. et al. // J. Alloys Compounds. 2017. V. 692. P. 980.
Fedorov P.P., Mayakova M., Alexandrov A. et al. // Inorganics. 2018. V. 6. P. 38.
Fedorov P.P., Alexandrov A.A. // J. Fluorine Chem. 2019. V. 227. Art. No. 109374.
Федоров П.П., Александров А.А., Брагина А.Г. и др. // Журн. неорг. хим. 2022. Т. 67. № 6. С. 794; Fedorov P.P., Alexandrov A.A., Bragina A.G. et al. // Russ. J. Inorg. Chem. 2022. V. 67. P. 861.
Морозов И.В., Карпова Е.В., Глазунова Т.Ю. и др. // Коорд. хим. 2016. Т. 42. № 10. С. 609.
Fedorova A.A., Fedulin A.I., Morozov I.V. // J. Fluorine Chem. 2015. V. 178. P. 173.
Глазунова Т.Ю., Болталин А.И., Федоров П.П. // Журн. неорг. хим. 2006. Т. 51. № 7. С. 1061; Glazunova T.Yu., Boltalin A.I., Fedorov A.A. // Russ. J. Inorg. Chem. 2006. V. 7. P. 983.
Buzoverov M.E., Glazunova T.Yu., Lermontova E.Kh. // Mendeleev Commun. 2022. V. 32. No. 2. P. 212.
Васильева А.А., Глазунова Т.Ю., Терещенко Д.С., Лермонтова Е.Х. // Тонкие хим. технол. 2021. Т. 16. № 4. С. 352; Vasilyeva A.A., Glazunova T.Yu., Tereshchenko D.S., Lermontova E.Kh. // Fine Chem. Tech. 2021. V. 16. No. 4. P. 352.
Федоров П.П. // Журн. неорг. хим. 1999. Т. 44. № 11. С. 1792; Fedorov P.P. // Russ. J. Inorg. Chem. 1999. V. 44. No. 11. P. 1703.