ELECTROCATALYTIC SYNTHESIS OF p-AMINOPHENOL 
USING Fe-Ag-COMPOSITES

N. M. Ivanova; Иванова Н. М.; Ya. A. Vissurkhanova; Висурханова Я. А.; E. A. Soboleva; Соболева Е. А.; Z. M. Muldakhmetov; Мулдахметов З. М.

doi:10.31857/S0424857023100067

ELECTROCATALYTIC SYNTHESIS OF p-AMINOPHENOL USING Fe-Ag-COMPOSITES

Authors: Ivanova N.M.¹, Vissurkhanova Y.A.¹, Soboleva E.A.¹, Muldakhmetov Z.M.¹
Affiliations:
1. LLP “Institute of Organic Synthesis and Coal Chemistry of the Republic of Kazakhstan”
Issue: Vol 59, No 10 (2023)
Pages: 632-642
Section: Articles
URL: https://journal-vniispk.ru/0424-8570/article/view/141827
DOI: https://doi.org/10.31857/S0424857023100067
EDN: https://elibrary.ru/WJJCKG
ID: 141827

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Abstract

p-Aminophenol was prepared by electrocatalytic hydrogenation of p-nitrophenol using Ag + Fe + Fe3O4 (or Fe2O3) composites as catalysts formed during heat treatment and electrochemical reduction of silver ferrite, AgFeO2. AgFeO2 samples were synthesized by co-precipitation method without and in the presence of a polymer (polyvinyl alcohol, polyvinylpyrrolidone). The effect of the polymers on the phase constitutions of metal composites formed at the stage of synthesis, during the heat treatment and electrochemical reduction was established. The high electrocatalytic activity of prepared Fe-Ag-containing composites in electrohydrogenation of p-nitrophenol with an increase of hydrogenation rate by 2.2-2.7 times in comparison with its electrochemical reduction in similar conditions was shown.

Keywords

p-aminophenol, electrocatalytic hydrogenation, p-nitrophenol, Fe-Ag catalysts, silver ferrite, structural-phase changes.

References

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