Novel Two-Stage Method of Preparing Graphitic Carbon Nitride Doped by Chlorine for Photocatalytic Hydrogen Evolution and Photocurrent Generation

A. V. Zhurenok; Журенок А. В.; D. V. Markovskaya; Марковская Д. В.; K. O. Potapenko; Потапенко К. О.; N. D. Sidorenko; Сидоренко Н. Д.; S. V. Cherepanova; Черепанова С. В.; A. A. Saraev; Сараев А. А.; E. Y. Gerasimov; Герасимов Е. Ю.; E. A. Kozlova; Козлова Е. А.

doi:10.31857/S0453881123030139

Novel Two-Stage Method of Preparing Graphitic Carbon Nitride Doped by Chlorine for Photocatalytic Hydrogen Evolution and Photocurrent Generation

Authors: Zhurenok A.V.¹, Markovskaya D.V.¹, Potapenko K.O.¹, Sidorenko N.D.¹, Cherepanova S.V.¹, Saraev A.A.¹, Gerasimov E.Y.¹, Kozlova E.A.¹
Affiliations:
1. Federal Research Center Boreskov Institute of Catalysis
Issue: Vol 64, No 3 (2023)
Pages: 276-286
Section: ARTICLES
URL: https://journal-vniispk.ru/0453-8811/article/view/136991
DOI: https://doi.org/10.31857/S0453881123030139
ID: 136991

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Abstract

In this work graphitic carbon nitride doped by chlorine was prepared by a two-stage technique at first. At the first stage melamine was hydrothermally treated with glucose, at the second stage the mixture of as-prepared melamine with ammonium chloride was calcined. The obtained samples were investigated by the set of methods: X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy, photoelectrochemical methods. All prepared photocatalysts was tested in the reaction of photocatalytic hydrogen production from basic solutions of triethanolamine. It was shown that the highest values of the catalytic activity and short-circuit current density were obtained over the photocatalyst preparing by calcination of the mixture containing 30% ammonium chloride and 70% melamine. The highest value of the catalytic activity was 1332 μmol h^–1 g^–1 and was more than the catalytic activity of carbon nitride preparing by the melamine calcination without another treatment in 22 times.

Keywords

carbon nitride, doped by chlorine, hydrogen production, photocatalysis, photocurrent, visible light

References

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