Ceria–Zirconia Supported Platinum Catalysts for Water Gas Shift Reaction: Influence of Support Composition

A. M. Gorlova; Горлова А. М.; V. P. Pakharukova; Пахарукова В. П.; O. A. Stonkus; Стонкус О. А.; V. N. Rogozhnikov; Рогожников В. Н.; A. Y. Gladky; Гладкий А. Ю.; P. V. Snytnikov; Снытников П. В.; D. I. Potemkin; Потемкин Д. И.

doi:10.31857/S0453881123040044

Ceria–Zirconia Supported Platinum Catalysts for Water Gas Shift Reaction: Influence of Support Composition

Authors: Gorlova A.M.¹^,2, Pakharukova V.P.¹^,2, Stonkus O.A.¹^,2, Rogozhnikov V.N.¹, Gladky A.Y.¹, Snytnikov P.V.¹, Potemkin D.I.¹^,2
Affiliations:
1. Boreskov Institute of Catalysis
2. Novosibirsk State University
Issue: Vol 64, No 4 (2023)
Pages: 447-456
Section: 7-я Международная школа-конференция молодых ученых “Катализ: от науки к промышленности”
URL: https://journal-vniispk.ru/0453-8811/article/view/137034
DOI: https://doi.org/10.31857/S0453881123040044
EDN: https://elibrary.ru/RQREQU
ID: 137034

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Abstract

The study is presented on the influence of the composition of a ceria-zirconia support on the structure and the activity in water gas shift reaction of platinum catalysts (Pt/Ce_0.75Zr_0.25O₂ и Pt/Ce_0.4Zr_0.5Y_0.05La_0.05O₂). The structure diagnostics of the samples were performed using high-resolution transmission electron microscopy, powder X-ray diffraction, CO chemisorption and X-ray atomic pair distribution function method. It was shown that the catalysts contain highly dispersed platinum particles not exceeding 2 nm in size. Platinum particles supported on Ce_0.75Zr_0.25O₂ are smaller due to the higher specific surface area of the support. The catalysts Pt/Ce_0.75Zr_0.25O₂ and Pt/Ce_0.4Zr_0.5Y_0.05La_0.05O₂ proved to have similar efficiency while having the same platinum content. It was assumed that the catalysts supported on Ce_0.4Zr_0.5Y_0.05La_0.05O₂ demonstrate a slightly higher turnover frequency per platinum surface atom, but it is likely compensated by the difference in the supported metal particle size.

Keywords

water gas shift, hydrogen purification, platinum catalyst, ceria-zirconia

References

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