Kinetics of the Reaction of Oxyethylation of Alcohols in Considering the Influence of Association. Kinetic Aspects of Association

B. Ya. Stul’; Стуль Б. Я.

doi:10.31857/S0453881123060187

Kinetics of the Reaction of Oxyethylation of Alcohols in Considering the Influence of Association. Kinetic Aspects of Association

Authors: Stul’ B.Y.¹
Affiliations:
1. Research Institute “Syntez”
Issue: Vol 64, No 6 (2023)
Pages: 710-719
Section: ARTICLES
URL: https://journal-vniispk.ru/0453-8811/article/view/231800
DOI: https://doi.org/10.31857/S0453881123060187
EDN: https://elibrary.ru/KRABGV
ID: 231800

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Abstract
About the authors
References
Supplementary files
Statistics

Abstract

It is assumed that in the reaction of alcohol oxyethylation, the kinetically independent unit is not a monomeric alcohol molecule, but a linear chain alcohol associate, consisting, on average, of n alcohol molecules. Тhe reaction rate is of the first order not by the gross concentration of alcohol, but by the concentration of these associates. It has been suggested that first-order reactions with respect to the associated component, which are widespread in liquid-phase chemical kinetics, take place as a result of the release of the reaction product from the associate.

Keywords

alcohol ethoxylation, kinetics, reaction order, association

About the authors

B. Ya. Stul’

Research Institute “Syntez”

Author for correspondence.
Email: b.st@mail.ru
Russia, 115088, Mosсow, Ugreshskaya st., 2

References

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