Kinetic Study of  para - tert -Butylcumene Oxidation in the Presence of  N -Hydroxyphthalimide

А. S. Frolov; Фролов А. С.; E. A. Kurganova; Курганова Е. А.; V. N. Sapunov; Сапунов В. Н.; R. A. Kozlovskiy; Козловский Р. А.; G. N. Koshel; Кошель Г. Н.; E. M. Yarkina; Яркина Е. М.

doi:10.31857/S0453881123060072

Kinetic Study of para-tert-Butylcumene Oxidation in the Presence of N-Hydroxyphthalimide

作者: Frolov А.S.¹, Kurganova E.A.¹, Sapunov V.N.², Kozlovskiy R.A.², Koshel G.N.¹, Yarkina E.M.¹
隶属关系:
1. Yaroslavl State Technical University
2. Mendeleev University of Chemical Technology of Russia
期: 卷 64, 编号 6 (2023)
页面: 720-729
栏目: ARTICLES
URL: https://journal-vniispk.ru/0453-8811/article/view/231806
DOI: https://doi.org/10.31857/S0453881123060072
EDN: https://elibrary.ru/KTUAWJ
ID: 231806

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详细

The kinetics of the oxidation of para-tert-butylcumene to hydroperoxide by molecular oxygen in the presence of N-hydroxyphthalimide has been studied. Based on the study of the regularities in the formation of hydroperoxide and non-target reaction products, a mathematical model of the process was obtained that adequately describes the change in the main components of the reaction concentration over time. The main role of N-hydroxyphthalimide is that it converts peroxide radicals into the corresponding hydroperoxides, thereby reducing the formation of non-target reaction products by reducing the quadratic termination rate. Simultaneously formed N-oxyphthalimide radicals increase the rate of hydrocarbon oxidation. Thus, the use of N-hydroxyphthalimide in hydrocarbon oxidation processes results in an increase in the rate and selectivity of hydroperoxide formation.

关键词

N-hydroxyphthalimide, oxidation, para-tert-butylcumene, mathematical modeling

参考

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