电邮这篇文章 Heterocyclization of 2-Acetylcyclopentanone
- 作者: Danagulyan G.G.1,2, Georgyan T.E.2, Boyakhchyan A.P.2, Danagulyan A.G.1,2
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隶属关系:
- Russian-Armenian University
- The Scientific Technological Center of Organic and Pharmaceutical Chemistry NAS RA
- 期: 卷 61, 编号 4 (2025)
- 页面: 393-403
- 栏目: ЭКСПЕРИМЕНТАЛЬНЫЕ СТАТЬИ
- URL: https://journal-vniispk.ru/0514-7492/article/view/307891
- DOI: https://doi.org/10.31857/S0514749225040056
- EDN: https://elibrary.ru/SDIXYJ
- ID: 307891
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详细
Based on 2-acetylcyclopentanone, the synthesis of various heterocycles has been studied, in particular, derivatives of pyrazole, pyrimidine, condensed systems of pyrazolo[1,5-a]pyrimidine and 1,2,4-triazolo[1,5-a]pyrimidine, as well as their methyl iodides. Due to the observed nuclear Overhauser effect (NOE), in a number of cases, the structure of the synthesized substances could be proven only by using the NOESY NMR spectroscopy technique. An effective method for using NMR spectroscopy to prove the structures of the synthesized substances is proposed, by obtaining their methyl iodides and then studying the spectra of the resulting salts.
作者简介
G. Danagulyan
Russian-Armenian University; The Scientific Technological Center of Organic and Pharmaceutical Chemistry NAS RA
Email: gevorg.danagulyan@rau.am
Yerevan, Armenia
T. Georgyan
The Scientific Technological Center of Organic and Pharmaceutical Chemistry NAS RAYerevan, Armenia
A. Boyakhchyan
The Scientific Technological Center of Organic and Pharmaceutical Chemistry NAS RAYerevan, Armenia
A. Danagulyan
Russian-Armenian University; The Scientific Technological Center of Organic and Pharmaceutical Chemistry NAS RAYerevan, Armenia
参考
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