Synthesis, properties and applications of oxide, oxofluoride and fluoride carbon polymers

Cover Page

Cite item

Full Text

Abstract

The paper presents original methods of synthesis and results of fluorination of natural and artificial polymers using the example of wood, cellulose, lignin, graphite oxide, carbon nanotubes and perfluoroalkene. The synthesized compounds have been studied using scanning electron microscopy, energy dispersion spectroscopy, chromatography-mass spectrometry, X-ray photoelectron spectroscopy. Fluorocarbon compounds have been tested as energy-intensive cathode materials for lithium and sodium chemical current sources, piezoelectric materials, as well as hydrophobic, antifriction, anti-wear coatings.

About the authors

A. K. Tsvetnikov

Institute of Chemistry, FEB RAS, Vladivostok, Russia

Email: tsvetnikov@ich.dvo.ru

L. A. Matveenko

Institute of Chemistry, FEB RAS, Vladivostok, Russia

Email: la.la.matv@gmail.com

V. G. Kuryavyi

Institute of Chemistry, FEB RAS, Vladivostok, Russia

Email: kvg@ich.dvo.ru

V. V. Korochentsev

Institute of Chemistry, FEB RAS, Vladivostok, Russia

Email: vkoroch@mail.ru

D. P. Opra

Institute of Chemistry, FEB RAS, Vladivostok, Russia

Email: ayacks@mail.ru

A. A. Sokolov

Institute of Chemistry, FEB RAS, Vladivostok, Russia

Email: alexsokol90@mail.ru

V. S. Egorkin

Institute of Chemistry, FEB RAS, Vladivostok, Russia

Email: egorkin@ich.dvo.ru

S. V. Gnedenkov

Institute of Chemistry, FEB RAS, Vladivostok, Russia

Email: svg21@hotmail.com

References

  1. Sandberg D., Kutnar A., Mantanis G. Wood modification technologies – a review.iForest–Biogeosciences and Forestry.2017;10(6):895–908.
  2. Nevarez L.A.M. et al. Biopolymer-based nanocomposites: effect of lignin acetylation in cellulose triacetate films.Sci. Technol. Adv. Mater.2011;12:1–16. doi: 10.1088/1468-6996/12/4/045006.
  3. Sarkanen K.V., Ludwig K.H. (Eds). Lignins. Moscow: Lesn. Prom-st’; 1975. 490 p. (In Russ.).
  4. Gribkov I.V. Chemical composition and structure of technical hydrolytic lignin: Diss. … Cand. of Chemistry: 05.21.03: approved 18.09.08. St. Petersburg; 2008. 142 p. (In Russ.).
  5. Method for producing a reagent-reducer of viscosity of drilling fluids: A. s. 1336531 USSR No. 3778357/04 / A.A. Uminsky, E.T. Karaseva, V.D. Gorodnov, T.L. Ermakova, P.S. Davydov, V.E. Oleynikov, A.K. Tsvetnikov, E.G. Ippolitov; declared 01.08.1984; published 10.09.1999, Bull. 25. Pt III. 629 p. (In Russ.).
  6. Method for producing a biocide based on lignin derivatives: Patent 2068417 Russian Federation No. 5031268/04 / A.K. Tsvetnikov, Yu.M. Kaplin; declared. 25.12.1991; published. 27.10.1996, Bull. 30. 341 p. (In Russ.).
  7. Tsvetnikov A.K., Ignatyeva L.N., Kaplin Yu.M., Buznik V.M. Processing of ligninusing conversion products and industrial waste.Chemistry for Sustainable Development. 2001;9:299–305. (In Russ.).
  8. Method for producing fluorinated carbon material: Patent 2036135 Russian Federation. No. 5042422/26 / A.K. Tsvetnikov, T.Yu. Nazarenko; declared 17.04.1992; published 27.05.1995, Bulletin 15. 142 p. (In Russ.).
  9. Opra D.P. et al. Electrode materials with improved characteristics for lithium and sodium electrochemical power sources: results and prospects.Vestnik of the FEB RAS.2021;(5):65–78. (In Russ.).
  10. Tkacheva N.I. et al. Cellulose modification is a promising direction in the creation of new materials.High-molecular Compounds. Series B.2013;55(8):1086–1107. (In Russ.). doi: 10.7868/S0507547513070179.
  11. Iijima S. Synthesis of Carbon Nanotubes.Nature.1991;354:56–58.
  12. Mickelson E.T. et al. Fluorination of single-wall carbon nanotubes.Chem. Phys. Lett.1998;296(1/2):188–194.
  13. Lee Y.-S. et al. Surface properties of fluorinated single-walled carbon nanotubes.J. Fluorine Chem.2003;120:99–104.
  14. Habasescu V.N. Covalent functionalization of carbon nanotubes: synthesis, properties and application of fluorinated derivatives.Uspekhi Chem.2011;80(8):239–760. (In Russ.).
  15. Tkachev A.G. et al. Strengthening of epoxy materials with fluorinated carbon nanotubes.Modern Problems of Science and Education.2014;(2). (In Russ.). URL: https://science-education.ru/ru/article/view?id=12620 (date of access: 24.04.2025).
  16. Brodie B.C. On the atomic weight of graphite.Phil. Trans. R. Soc. Lond. A.1859;149:249–259.
  17. Hummers W.S., Offeman R.E. Preparation of Graphitic Oxide.J. Am. Chem. Soc.1958;80/6:1339–1339.
  18. Songfeng Pei et al. Green synthesis of graphene oxide by seconds timescale water electrolytic oxidation.Nature Communications.2018;9(1):1–9. https://doi.org/10.1038/s41467-017-02479-z
  19. Tsvetnikov A.K., Nazarenko T.Yu., Matveenko L.A., Mishchenko N.M. Effect of the intercalation stage on the composition and properties of graphite oxides.J. Inorg. Chem.1997;42(5):705–710. (In Russ.).
  20. Tsvetnikov A.K., Nazarenko T.Yu., Matveenko L.A., Nikolenko Yu.M. Synthesis and study of graphite fluoroxides.J. Inorg. Chem.1992;37(3):483–490. (In Russ.).
  21. Piezoelectric material: A. s. 1510635 Russian Federation No. 4352276/25 / Tsvetnikov A.K., Glukhomanyuk G.G., Volkov D.A.; declared 05.12.1987, published 10.09.1999, Bull. 25. 652 p. (In Russ.).
  22. Method for producing graphite oxyfluoride: a. s. 1683284 Russian Federation No. 4783588/26 / A.K. Tsvetnikov, A.A. Uminsky, A.F. Manukhin; declared 28.12.1989; published 10.09.1999, Bull. 25. 628 p. (In Russ.).
  23. Kharitonov A.P. Practical applications of the direct fluorination of polymers.J. Fluorine Chem.2000;(103):123–127.
  24. Kharitonov A.P. Direct fluorination of polymers – from fundamental research to industrial applications.Progress in Organic Coatings.2008;61:192–204. doi: 10.1016/j.porgcoat.2007.09.027.
  25. Nazarov V.G., Stolyarov V.P., Baranov V.A., Evlampieva L.A. Fluorinated rubbers with improved tribotechnical properties.Russian Chemical Journal.2008;52(3):45−55. (In Russ.).
  26. Slavyansky A.K. et al. Chemical technology of wood. Moscow; 1962. 581 p. (In Russ.).
  27. Pavlov A.D., Sukhoverkhov S.V., Tsvetnikov A.K. Using pyrolytic chromatograph mass spectrometry to determine the composition of Forum and its fractions.Vestnik of the FEB RAS.2011;(5):51–55. (In Russ.).
  28. Method for producing perfluoroparaffins: Patent. 2814664 Russian Federation No. 2023122237 / A.K. Tsvetnikov, L.A. Matveenko, V.S. Egorkin; declared. 25.08.2023, publ. 04.03.2024, Bull.7. 3 p. (In Russ.).

Supplementary files

Supplementary Files
Action
1. JATS XML
Download

Copyright (c) 2025 Russian Academy of Sciences

Согласие на обработку персональных данных

 

Используя сайт https://journals.rcsi.science, я (далее – «Пользователь» или «Субъект персональных данных») даю согласие на обработку персональных данных на этом сайте (текст Согласия) и на обработку персональных данных с помощью сервиса «Яндекс.Метрика» (текст Согласия).