Synthesis of complex oxides in plasma of pulsed high-voltage discharge
- Authors: Kuryavyi V.G.1, Tkachenko I.A.1, Gerasimenko A.V.1
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Affiliations:
- Institute of Chemistry, FEB RAS
- Issue: No 4 (2025)
- Pages: 97-108
- Section: Advanced materials
- URL: https://journal-vniispk.ru/0869-7698/article/view/351728
- DOI: https://doi.org/10.7868/S3034530825040085
- ID: 351728
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Abstract
This article demonstrates two fast methods for synthesizing complex oxides in air high-voltage pulsed discharge plasma. In one of them, a powder containing CuO/Cu2O/Y2O3/Y2BaCuO/YBa2Cu3O6,32was synthesized, from which CuO/YBa2Cu3O6,91composite was obtained by calcination, including a superconducting phase below 87 K. In the other variant, Cr2NiO4/NiO/Ni composite was synthesized. The magnetic properties of the obtained substances were studied. The methods can be used for the rapid synthesis of high-temperature superconductors with a variety of oxide compositions and other complex oxides in order to search for new functional materials.
About the authors
V. G. Kuryavyi
Institute of Chemistry, FEB RAS
Email: kvg@ich.dvo.ru
Vladivostok, Russia
I. A. Tkachenko
Institute of Chemistry, FEB RAS
Email: tkachenko@ich.dvo.ru
Vladivostok, Russia
A. V. Gerasimenko
Institute of Chemistry, FEB RAS
Email: gerasimenko(at)@ich.dvo.ru
Vladivostok, Russia
References
- Abakumov A.M., Antipov E.V., Kovba L.M., Kopnin E.M., Putilin S.N., Panchenko R.V. Complex oxides with coherent intergrowth structures.Uspekhi Khimii.1995;64(8):769–780. (In Russ.).
- Istomin S.Ya., Lyskov N.V., Mazo G.N., Antipin E.V. Electrode materials based on complex d-metal oxides for symmetric solid oxide fuel cells.Uspekhi Khimii.2021;90(6):644–676. (In Russ.).
- Wu M.K., Ashburn J.R., Torng C.J., Hor P.H., Meng R.L., Gao L., Huang Z.J., Wang Y.Q., Chu C.W. Superconductivity at 93 K in a new mixed-phase Yb–Ba–Cu–O compound system at ambient pressure.Phys Rev Lett.1987;58(9):908–910. doi: 10.1103/PhysRevLett.58.908. PMID: 10035069.
- Balaev D.A., Semenov S.V., Gokhfeld D.M., Petrov M.I. Properties of the small magnetic hysteresis loop of granular HTSCs: range of existence, residual magnetization and relaxation of magnetization.Physics of the Solid State.2024;66(4):02–05. (In Russ.).
- Roa1 J.J., Dias F.T., Segarra M. Magnetical Response and Mechanical Properties of High Temperature Superconductors, YBaCu3O7-X Materials. In: Superconductors – Properties, Technology, and Applications.April 20, 2012.doi: 10.5772/1810ISBN978-953-51-0545-9.
- Sloczynski J., Ziolkowski J., Grzybowska B., Grabowski R., Jachewicz D., Wcislo K., Gengembre L. Oxidative dehydrogenation of propane on NixMg1-xAl2O4and NiCr2O4spinels.J. Catal.1999;187:410–418.
- Honeybourne C.L., Rasheed R.K. Nitrogen dioxide and volatile sulfide sensing properties of copper, zinc and nickel chromite.J. Mater. Chem.1996;6:277–283.
- Schoonman J., Dekker J.P., Broers J.W., Kiwiet N.J. Electrochemical vapor deposition of stabilized zirconia and interconnection materials for solid oxide fuel cells.Solid State Ion.1991;46:299–308.
- Maignan A., Martin C., Singh K., Simon Ch., Lebedev O.I., Turner S. From spin induced ferroelectricity to dipolar glasses: Spinel chromites and mixed delafossites.Journal of Solid State Chemistry.2012;195:41–49.
- Younisa M., Saleemb M., Atiqa S., Naseema S. Magnetic phase transition and magneto-dielectric analysis of spinel chromites: MCr2O4(M = Fe, Co and Ni).Ceramics International.2018;44:10229–10235.
- Nogues J., Schuller I.K., Exchange Bias.Journal of Magnetism and Magnetic Materials.1999;192(2):203–232. doi: 10.1016/S0304-8853(98)00266-2.
- Ovejero J.G., Godinho V., Lacroix B., García M.A., Hernando A., Asunción F. Exchange bias and two steps magnetization reversal in porous Co/CoO laye.Materials & Design.2019;171. 107691.
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