Email this article Dehydration of 2,3-butanediol over zeolite catalysts
- Authors: Nikitina M.A.1, Sushkevich V.L.1, Ivanova I.I.1
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Affiliations:
- Faculty of Chemistry
- Issue: Vol 56, No 3 (2016)
- Pages: 230-236
- Section: Article
- URL: https://journal-vniispk.ru/0965-5441/article/view/178467
- DOI: https://doi.org/10.1134/S0965544116030099
- ID: 178467
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Abstract
2,3-Butanediol as a product of biomass processing is a cheap alternative raw material for synthesis of methyl ethyl ketone (MEK) and butadiene-1,3. The catalytic activity of Al- and Zr-containing BEA zeolites and an alumina-based catalyst in 2,3-butanediol dehydration has been investigated. It has been shown that the presence of Brönsted (H-BEA) or Lewis (Al2O3) sites leads to the selective formation of MEK and the combination of two types of sites (Zr-BEA) facilitates the formation of heavy products of condensation.
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About the authors
M. A. Nikitina
Faculty of Chemistry
Email: IIIvanova@phys.chem.msu.ru
Russian Federation, Moscow
V. L. Sushkevich
Faculty of Chemistry
Email: IIIvanova@phys.chem.msu.ru
Russian Federation, Moscow
I. I. Ivanova
Faculty of Chemistry
Author for correspondence.
Email: IIIvanova@phys.chem.msu.ru
Russian Federation, Moscow
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