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An ultrahigh-resolution mass spectrometry study of ozonation products of petroleum sulfur compounds


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Abstract

Potential use of ultrahigh-resolution mass spectrometry for determination of sulfur-containing components of petroleum before and after ozonation has been described. The chemical composition of the petroleum before and after ozonation has been determined using a Fourier transform ion-cyclotron mass spectrometer with soft ionization techniques: atmospheric-pressure photoionization and positive- or negative-ion electrospray ionization. The article presents the main trends of change in the composition of petroleum sulfur components in the ozonation process as revealed on the basis of ultrahigh-resolution mass spectra.

About the authors

A. V. Stavitskaya

Gubkin Russian State University of Oil and Gas

Author for correspondence.
Email: stavitsko@mail.ru
Russian Federation, Moscow

M. L. Konstantinova

Emanuel Institute of Biochemical Physics of Russian Academy of Sciences

Email: safieva@mail.ru
Russian Federation, Moscow

R. Z. Safieva

Gubkin Russian State University of Oil and Gas; Saint-Petersburg Mining University

Author for correspondence.
Email: safieva@mail.ru
Russian Federation, Moscow; St. Petersburg

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