Hydroconversion of rosin acids in the presence of Pt-containing Al–HMS mesoporous aluminosilicate


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The hydroconversion of a mixture of rosin acids over a Pt-containing mesoporous aluminosilicate catalyst has been studied. It has been shown that in a temperature range of 300–350°C at pressures of 30–50 atm and a feedstock/catalyst weight ratio of 20/1, rosin acids undergo complete decarboxylation to form naphthenic and naphthene-aromatic hydrocarbons. Under optimum process conditions, the yield of diesel fuel hydrocarbons is more than 85%. The resulting fraction can be used as a fuel component.

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A. Kulikov

Topchiev Institute of Petrochemical Synthesis

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Email: akulikov@ips.ac.ru
俄罗斯联邦, Moscow

M. Onishchenko

Topchiev Institute of Petrochemical Synthesis

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Email: onishchenko@ips.ac.ru
俄罗斯联邦, Moscow

A. Maksimov

Topchiev Institute of Petrochemical Synthesis; Faculty of Chemistry

Email: onishchenko@ips.ac.ru
俄罗斯联邦, Moscow; Moscow

S. Lysenko

Faculty of Chemistry

Email: onishchenko@ips.ac.ru
俄罗斯联邦, Moscow

E. Karakhanov

Faculty of Chemistry

Email: onishchenko@ips.ac.ru
俄罗斯联邦, Moscow

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