Direct conversion of ethanol and fusel oils to alkane–aromatic hydrocarbons in the presence of a pilot Pd–Zn/TsVM catalyst


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The conversion of ethanol and fusel oils to a С3–С12 alkane–aromatic fraction with high activity and selectivity in the presence of the Pd–Zn/TsVM pilot catalyst has been demonstrated. It has been shown that the ethanol conversion to alkanes and aromatic hydrocarbons in the presence of this catalyst proceeds by various routes to give ethylene and diethyl ether as intermediate products providing a 90–95% yield on the converted ethanol carbon basis for the target С3–С12 fraction containing up to 40% of branched alkanes.

作者简介

A. Chistyakov

Topchiev Institute of Petrochemical Synthesis; Moscow Institute of Physics and Technology (State University)

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Email: chistyakov@ips.ac.ru
俄罗斯联邦, Moscow; Dolgoprudnyi, Moscow oblast

M. Tsodikov

Topchiev Institute of Petrochemical Synthesis; Moscow Institute of Physics and Technology (State University)

Email: chistyakov@ips.ac.ru
俄罗斯联邦, Moscow; Dolgoprudnyi, Moscow oblast

M. Chudakova

Topchiev Institute of Petrochemical Synthesis

Email: chistyakov@ips.ac.ru
俄罗斯联邦, Moscow

M. Gubanov

Topchiev Institute of Petrochemical Synthesis

Email: chistyakov@ips.ac.ru
俄罗斯联邦, Moscow

P. Zharova

Topchiev Institute of Petrochemical Synthesis; Moscow Institute of Physics and Technology (State University)

Email: chistyakov@ips.ac.ru
俄罗斯联邦, Moscow; Dolgoprudnyi, Moscow oblast

Z. Bukina

Topchiev Institute of Petrochemical Synthesis

Email: chistyakov@ips.ac.ru
俄罗斯联邦, Moscow

N. Kolesnichenko

Topchiev Institute of Petrochemical Synthesis

Email: chistyakov@ips.ac.ru
俄罗斯联邦, Moscow

A. Gekhman

Moscow Institute of Physics and Technology (State University); Kurnakov Institute of General and Inorganic Chemistry

Email: chistyakov@ips.ac.ru
俄罗斯联邦, Dolgoprudnyi, Moscow oblast; Moscow

S. Khadzhiev

Topchiev Institute of Petrochemical Synthesis

Email: chistyakov@ips.ac.ru
俄罗斯联邦, Moscow

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