Guaiacol Hydrogenation in an Aqueous Medium in the Presence of a Palladium Catalyst Supported on a Mesoporous Dendrimer-Containing Polymer

E. A. Karakhanov; M. P. Boronoev; T. Yu. Filippova; A. L. Maksimov

doi:10.1134/S0965544118050080

Guaiacol Hydrogenation in an Aqueous Medium in the Presence of a Palladium Catalyst Supported on a Mesoporous Dendrimer-Containing Polymer

Authors: Karakhanov E.A.¹, Boronoev M.P.¹, Filippova T.Y.¹, Maksimov A.L.¹^,2
Affiliations:
1. Faculty of Chemistry
2. Topchiev Institute of Petrochemical Synthesis
Issue: Vol 58, No 5 (2018)
Pages: 407-411
Section: Article
URL: https://journal-vniispk.ru/0965-5441/article/view/180172
DOI: https://doi.org/10.1134/S0965544118050080
ID: 180172

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Abstract

Guaiacol hydrogenation in an aqueous medium in the presence of a palladium catalyst supported on a mesoporous dendrimer-containing polymer and the effect of addition of sulfuric acid to the catalyst system have been studied. It has been found that the main hydrogenation product is 2-methoxycyclohexanol. After the addition of sulfuric acid to the catalyst system, the reaction mechanism significantly changes and cyclohexanol becomes the main hydrogenation product.