The Effect of the Active Component Content on the Catalytic Activity of Nickel Sulfide Catalysts in Olefin Synthesis from Stearic Acid
- 作者: Katsman E.A.1, Danyushevsky V.Y.1, Karpov V.M.1, Kuznetsov P.S.1, Shishilov O.N.1, Berenblyum A.S.1
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隶属关系:
- Institute of Fine Chemical Technologies (Moscow Technological University)
- 期: 卷 59, 编号 6 (2019)
- 页面: 622-628
- 栏目: Article
- URL: https://journal-vniispk.ru/0965-5441/article/view/180909
- DOI: https://doi.org/10.1134/S0965544119060112
- ID: 180909
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详细
The effect of active component content on the catalytic activity of supported sulfide catalysts in the synthesis of C17 olefins from stearic acid has been studied. It has been shown that an increase in the nickel content leads to a decrease in the catalyst activity; in addition, there is a negative correlation between the activity and the fraction of large particles on the support surface. The highest heptadecene selectivity (50–60%) is observed for alumina-supported catalysts owing to the higher degree of dispersion of the active component.
作者简介
E. Katsman
Institute of Fine Chemical Technologies (Moscow Technological University)
编辑信件的主要联系方式.
Email: katsman@aha.ru
俄罗斯联邦, Moscow
V. Danyushevsky
Institute of Fine Chemical Technologies (Moscow Technological University)
Email: katsman@aha.ru
俄罗斯联邦, Moscow
V. Karpov
Institute of Fine Chemical Technologies (Moscow Technological University)
Email: katsman@aha.ru
俄罗斯联邦, Moscow
P. Kuznetsov
Institute of Fine Chemical Technologies (Moscow Technological University)
Email: katsman@aha.ru
俄罗斯联邦, Moscow
O. Shishilov
Institute of Fine Chemical Technologies (Moscow Technological University)
Email: katsman@aha.ru
俄罗斯联邦, Moscow
A. Berenblyum
Institute of Fine Chemical Technologies (Moscow Technological University)
Email: katsman@aha.ru
俄罗斯联邦, Moscow
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