A Nanospherical Mesoporous Ruthenium-Containing Polymer as a Guaiacol Hydrogenation Catalyst


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

A hybrid catalyst is synthesized using ruthenium nanoparticles deposited on a nanospherical mesoporous polymer. Catalytic properties are studied in guaiacol hydrogenation at a temperature of 200–250°С and a hydrogen pressure of 5.0 MPa. Effect of solvent and catalytic additives on the reaction is investigated. It is shown that the synthesized catalyst exhibits the highest activity in guaiacol hydrodeoxygenation in the two-phase system water/n-dodecane and when the reaction is carried out in the presence of scandium triflate.

About the authors

M. P. Boronoev

Faculty of Chemistry, Moscow State University

Author for correspondence.
Email: maxbv04@gmail.com
Russian Federation, Moscow, 119991

I. I. Shakirov

Faculty of Chemistry, Moscow State University

Email: maxbv04@gmail.com
Russian Federation, Moscow, 119991

V. I. Ignat’eva

Faculty of Chemistry, Moscow State University

Email: maxbv04@gmail.com
Russian Federation, Moscow, 119991

A. L. Maximov

Faculty of Chemistry, Moscow State University; Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: maxbv04@gmail.com
Russian Federation, Moscow, 119991; Moscow, 119991

E. A. Karakhanov

Faculty of Chemistry, Moscow State University

Email: maxbv04@gmail.com
Russian Federation, Moscow, 119991

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2019 Pleiades Publishing, Ltd.