Email this article A Nanospherical Mesoporous Ruthenium-Containing Polymer as a Guaiacol Hydrogenation Catalyst
- Authors: Boronoev M.P.1, Shakirov I.I.1, Ignat’eva V.I.1, Maximov A.L.1,2, Karakhanov E.A.1
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Affiliations:
- Faculty of Chemistry, Moscow State University
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Issue: Vol 59, No 12 (2019)
- Pages: 1300-1306
- Section: Article
- URL: https://journal-vniispk.ru/0965-5441/article/view/181026
- DOI: https://doi.org/10.1134/S096554411912003X
- ID: 181026
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Abstract
A hybrid catalyst is synthesized using ruthenium nanoparticles deposited on a nanospherical mesoporous polymer. Catalytic properties are studied in guaiacol hydrogenation at a temperature of 200–250°С and a hydrogen pressure of 5.0 MPa. Effect of solvent and catalytic additives on the reaction is investigated. It is shown that the synthesized catalyst exhibits the highest activity in guaiacol hydrodeoxygenation in the two-phase system water/n-dodecane and when the reaction is carried out in the presence of scandium triflate.
About the authors
M. P. Boronoev
Faculty of Chemistry, Moscow State University
Author for correspondence.
Email: maxbv04@gmail.com
Russian Federation, Moscow, 119991
I. I. Shakirov
Faculty of Chemistry, Moscow State University
Email: maxbv04@gmail.com
Russian Federation, Moscow, 119991
V. I. Ignat’eva
Faculty of Chemistry, Moscow State University
Email: maxbv04@gmail.com
Russian Federation, Moscow, 119991
A. L. Maximov
Faculty of Chemistry, Moscow State University; Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: maxbv04@gmail.com
Russian Federation, Moscow, 119991; Moscow, 119991
E. A. Karakhanov
Faculty of Chemistry, Moscow State University
Email: maxbv04@gmail.com
Russian Federation, Moscow, 119991
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