Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes
- Авторлар: Dekhtyar’ T.F.1, Vostrikova O.S.2, Zlotskii S.S.2, Bogomazova A.A.1, Mikhailova N.N.2
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Мекемелер:
- Bashkir State University, Sterlitamak Branch
- Ufa State Petroleum Technological University
- Шығарылым: Том 59, № 6 (2019)
- Беттер: 650-655
- Бөлім: Article
- URL: https://journal-vniispk.ru/0965-5441/article/view/180923
- DOI: https://doi.org/10.1134/S0965544119060082
- ID: 180923
Дәйексөз келтіру
Аннотация
The interaction of 2-monosubstituted 1,3-dioxolanes with 3-hexyl-1-ethylaluminacyclopentane leads to the cleavage of the Al–C bond of the metallocycle and the formation of ethylene glycol monoethers after hydrolysis of the resulting reaction mixture. Catalytic amounts of ZrCl4 or Ni(acac)2 activate the process. The reaction of 2-monosubstituted 1,3-dioxolanes with 1-ethyl-3-naphthylaluminacyclopentane yields the product of cleavage of the exocyclic Al–Et bond of aluminacyclopentane.
Негізгі сөздер
Авторлар туралы
T. Dekhtyar’
Bashkir State University, Sterlitamak Branch
Хат алмасуға жауапты Автор.
Email: dekhtyartf@mail.ru
Ресей, Sterlitamak, Bashkortostan, 453103
O. Vostrikova
Ufa State Petroleum Technological University
Email: dekhtyartf@mail.ru
Ресей, Ufa, Bashkortostan, 450062
S. Zlotskii
Ufa State Petroleum Technological University
Email: dekhtyartf@mail.ru
Ресей, Ufa, Bashkortostan, 450062
A. Bogomazova
Bashkir State University, Sterlitamak Branch
Email: dekhtyartf@mail.ru
Ресей, Sterlitamak, Bashkortostan, 453103
N. Mikhailova
Ufa State Petroleum Technological University
Email: dekhtyartf@mail.ru
Ресей, Ufa, Bashkortostan, 450062
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