Kinetic Analysis of Isobutylene Synthesis from Ethanol in the Presence of ZnO/ZrO2
- Авторы: Ponomareva O.A.1,2, Shaposhnik P.A.2, Konnov S.V.1, Kolozhvari B.A.1,2, Ivanova I.I.1,2
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Учреждения:
- Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Faculty of Chemistry, Moscow State University
- Выпуск: Том 59, № 8 (2019)
- Страницы: 935-940
- Раздел: Article
- URL: https://journal-vniispk.ru/0965-5441/article/view/180980
- DOI: https://doi.org/10.1134/S0965544119080164
- ID: 180980
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Аннотация
Kinetic analysis of isobutylene synthesis from ethanol in the presence of a ZnO/ZrO2 catalyst synthesized by incipient wetness impregnation of zirconium hydroxide with zinc nitrate has been conducted. Analysis data have been used to determine primary, secondary, stable, and unstable products. The selectivity for the reaction products and the order of their formation have been determined. A general scheme of the reaction routes for ethanol conversion to isobutylene has been proposed.
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Об авторах
O. Ponomareva
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Автор, ответственный за переписку.
Email: oaponomareva@phys.chem.msu.ru
Россия, Moscow, 119991; Moscow, 119991
P. Shaposhnik
Faculty of Chemistry, Moscow State University
Email: oaponomareva@phys.chem.msu.ru
Россия, Moscow, 119991
S. Konnov
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: oaponomareva@phys.chem.msu.ru
Россия, Moscow, 119991
B. Kolozhvari
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Email: oaponomareva@phys.chem.msu.ru
Россия, Moscow, 119991; Moscow, 119991
I. Ivanova
Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University
Email: oaponomareva@phys.chem.msu.ru
Россия, Moscow, 119991; Moscow, 119991
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