Email this article Simulation of differential pulse polarography of irreversible EC mechanism
- Authors: Lovric M.1
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Affiliations:
- Department of Marine and Environmental Research
- Issue: Vol 52, No 10 (2016)
- Pages: 938-942
- Section: Article
- URL: https://journal-vniispk.ru/1023-1935/article/view/188173
- DOI: https://doi.org/10.1134/S1023193516100086
- ID: 188173
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Abstract
A reversible electrode reaction that is followed by totally irreversible chemical reaction is investigated theoretically. The influence of chemical reaction on two components of the net response of differential pulse polarogram is analyzed. It is demonstrated that this EC mechanism depends on two kinetic parameters and that their critical values can be used for the measurement of the rate constant of chemical reaction.
About the authors
Milivoj Lovric
Department of Marine and Environmental Research
Author for correspondence.
Email: mlovric@irb.hr
Croatia, Zagreb, 10000
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