Email this article Electrochemical dehalogenation of polytrifluorochloroethylene
- Authors: Stepanov A.A.1, Buzin M.I.1, Kononova E.G.1, Sosenkin V.E.2, Vol’fkovich Y.M.2
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Affiliations:
- Nesmeyanov Institute of Organoelement Compounds
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 53, No 5 (2017)
- Pages: 555-559
- Section: Short Communications
- URL: https://journal-vniispk.ru/1023-1935/article/view/188742
- DOI: https://doi.org/10.1134/S1023193517050135
- ID: 188742
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Abstract
The electrochemical reduction of polytrifluorochloroethylene suspended in an electrolyte using organic electron transfer mediators led to surface modification of the polymer. Pyrolysis of the reduction product was accompanied by the formation of a highly porous thermally stable polycarbon material with pore sizes in a very wide range, approximately from 1 to 105 nm.
About the authors
A. A. Stepanov
Nesmeyanov Institute of Organoelement Compounds
Author for correspondence.
Email: stepanov@ineos.ac.ru
Russian Federation, Moscow, 119991
M. I. Buzin
Nesmeyanov Institute of Organoelement Compounds
Email: stepanov@ineos.ac.ru
Russian Federation, Moscow, 119991
E. G. Kononova
Nesmeyanov Institute of Organoelement Compounds
Email: stepanov@ineos.ac.ru
Russian Federation, Moscow, 119991
V. E. Sosenkin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: stepanov@ineos.ac.ru
Russian Federation, Moscow, 119071
Yu. M. Vol’fkovich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: stepanov@ineos.ac.ru
Russian Federation, Moscow, 119071
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