Preparation and characterization of cerium doped LaCoO3 perovskite

Abstract

Cerium doped lanthanum cobaltite perovskites La_1–xCe_xCoO₃ with x = 0, 0.2, 0.4 were prepared by the sol-gel method (calcined for 5 h at 750°C) and characterized by X-ray diffraction, X-ray absorption, energy dispersive X-ray spectroscopy and Brunauer–Emmett–Teller surface area analysis. The results showed that the cerium doping promoted the structural transformation of LaCoO₃ from rhombohedral into cubic structure. High specific surface area and small crystallite size were achieved at x = 0.2. The X-ray absorption results confirmed the formation of compound La_1–xCe_xCoO₃.