Mechanism of the Effect of Gamma Irradiation on the Surface Properties of Polytetrafluoroethylene


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Abstract

Changes in the work of adhesion γSL of polar and nonpolar liquids, as well as the dispersion and polar components of the surface energy of γS suspension-polymerized polytetrafluoroethylene (PTFE) as a function of the gamma-radiation dose are analyzed quantitatively. A physicochemical model for increasing the work of adhesion γSL of a polar liquid is proposed. The model is based on the formation of a double electrostatic layer at the phase interface due to ion-dipole interaction.

About the authors

A. Yu. Obvintsev

Karpov Institute of Physical Chemistry

Author for correspondence.
Email: obvsun@mail.ru
Russian Federation, Moscow, 103064

S. A. Serov

Karpov Institute of Physical Chemistry

Email: obvsun@mail.ru
Russian Federation, Moscow, 103064

N. V. Sadovskaya

Karpov Institute of Physical Chemistry

Email: obvsun@mail.ru
Russian Federation, Moscow, 103064

S. A. Khatipov

Nesmeyanov Institute of Organoelement Compounds

Email: obvsun@mail.ru
Russian Federation, Moscow, 119991

V. M. Bouznik

All-Russian Scientific Research Institute of Aviation Materials

Email: obvsun@mail.ru
Russian Federation, Moscow, 105005

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