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Vol 121, No 6 (2017)

Article

Investigation of Thermal and Epithermal Neutron Flux Distributions in Universal Nuclear Icebreaker Fuel Assemblies

Samoilov O.B., Alekseev V.I., Galitskikh V.Y., Belin A.V., Zaglyadnov A.N., Samusenkov V.V., Ust’yantsev S.G.

Abstract

The results of experimental investigations of the spatial and energy distributions of the thermal and epithermal neutrons in a cassette fuel assembly, similar in design to that developed for the RITM-200 reactor core in the universal nuclear icebreaker, are presented. The measurements were performed using activation detectors with the isotopes 63Cu, 55Mn, and 197Au. It is shown that the structural nonuniformities of the fuel assembly (central water cavity, reactivity compensation system absorbing rod, strongly screened rods with consumable absorber) create significant thermal neutron flux nonuniformity over the cross-section of a fuel assembly. The flux distribution of epithermal neutrons with energy >0.4 eV is almost uniform. The experimental data are supported by calculations.

Atomic Energy. 2017;121(6):389-396
pages 389-396 views

Experimental Validation of the Technical Characteristics of a Steam-Generator Cassette in the RITM-200 Reactor

Bakhmet’ev A.M., Bykh O.A., Shchekin D.V., Makarov O.V., Kamnev M.A., Antonenkov M.A.

Abstract

A high-efficiency once-through steam generator is used in the RITM-200 reactor for the universal nuclear icebreaker. The new design necessitated experimental validation of the technical characteristics of the steam generator taking into account the integral arrangement of the steam-generating block. To this end a model of the steam-generator cassette was developed and tested at OKBM Afrikantov. The experimental studies of the model of the steam-generator cassette confirmed the heat-engineering and hydrodynamic design characteristics of the steam generator in the RITM-200 reactor.

Atomic Energy. 2017;121(6):397-401
pages 397-401 views

Comparison and Analysis of Residual Heat Removal Systems of Reactors in Station Blackout Accidents

Aminov R.Z., Egorov A.N.

Abstract

A comparative analysis is performed of emergency cool-down systems of water-cooled reactors, using passive heat-removal systems. The use of such a system reduces the likelihood of serious accidents with core damage at NPP but the capital investment and associated operating costs are higher. Auxiliary expenditures on maintaining this system in a standby mode are also required. A scheme combining active and passive cool-down systems is proposed owing to the rejection of air heat-exchangers-condensers of the passive heat-removal system and the installation of an auxiliary low-capacity steam turbogenerator is proposed. A comparative technical-economic analysis of the proposed combined cool-down system and an air passive heat-removal system is performed. The calculations show that at comparable safety levels such a system makes it possible to reduce capital and total operating expenses for NPP located in all climatic belts.

Atomic Energy. 2017;121(6):402-408
pages 402-408 views

Modeling of the Thermodynamic Interaction of Beryllium Minerals with Different Opening Agents

Kol’tsov V.Y., Yudina T.B., Zakharov A.A., Semenov A.A., Lizunov A.V., Demin A.V.

Abstract

Modeling of the thermodynamic interaction of beryllium minerals with different opening agents is performed in order to validate the proposed methods of opening beryllium orr at the Ermakovskoe deposit and the structural design of technological equipment blocks. It is found that when beryllium minerals interact with sulfuric acid and alkali the following stability sequences of the minerals are observed: bertrandite–phenakite–beryl with acid and the reverse sequence with alkali. In the case of alkali, the opening of the composition of the reaction products depends on the alkali consumption.

Atomic Energy. 2017;121(6):409-414
pages 409-414 views

Analysis of Experimental Data on Gas Release and Swelling of Uranium Mononitride Fuel Irradiated in the BR-10 Reactor

Porollo S.I., Ivanov S.N., Marinenko E.E., Zabud’ko L.M.

Abstract

The results of an investigation of gas release and swelling of uranium mononitride fuel after irradiation in standard and experimental fuel assemblies in the BR-10 reactor in the burnup range 3.4–8.4% h.a. are presented and analyzed. The results obtained were used to verify the fuel code DRAKON.

Atomic Energy. 2017;121(6):415-423
pages 415-423 views

Production of Uranium Hexafluoride with Low 234U Content in a Cascade with Intermediate Product

Palkin V.A.

Abstract

A scheme is proposed for purifying native uranium hexafluoride in a cascade with one feed stream, two product streams, and one waste stream. The cascade is reckoned as quasi-ideal with adjustments of the obtained 235U concentration for the prescribed content in the external streams. A product with native 235U concentration and low 234U concentration is produced in the intermediate product stream of the cascade. Low-enrichment uranium hexafluoride intended for fabricating nuclear fuel is obtained in the main product stream. A high-quality diluent for high-enrichment uranium or low-enrichment uranium hexafluoride with 234U content less than the ASTM C 996–10 limit norm by a factor of 1.5–2.5 can be produced from the intermediate product.

Atomic Energy. 2017;121(6):424-429
pages 424-429 views

Synthesis of Inter-Reticular Anionites for Uranium Sorption

Balanovskii N.V., Shurmel’ L.B., Tsarenko N.A.

Abstract

A new method for modifying ion-exchange resins was developed in order to improve the performance of industrial ionites used in the extraction of uranium. It consists in using polymer matrices made from several interpenetrating low-linkage polymer networks, which are obtained by repeated polymerization of a mixture of mono- and divinyl monomers, solvating the primary copolymer. Using this method, inter-reticular anionites for uranium sorption were synthesized by the means of double copolymerization of styrene and divinyl benzene followed by chloromethylation of the obtained matrix and amination of the chloromethylated copolymer by pyridine. It is shown that in terms of the uranium sorption capacity and kinetic characteristics inter-reticular anionites surpass the best foreign-made resins by factors of 1.3–1.8.

Atomic Energy. 2017;121(6):430-434
pages 430-434 views

Concentration Dependence of the Rate of Catalytic Isotopic Exchange of Hydrogen with Water Vapor on the Catalyst RKhTU-3SM

Tkachenko V.A., Ovcharov A.V., Rozenkevich M.B.

Abstract

One method of separating hydrogen isotopes is chemical isotopic exchange of hydrogen with liquid water, combined with electrolysis of water. At present, different mathematical models are used to calculate the characteristics of newly developed setups. They all have the problem of inadequate data on the characteristics of the chemical isotopic exchange process occurring at medium and high deuterium concentrations. The present work is devoted to investigating one stage of chemical isotopic exchange – catalytic isotopic exchange between hydrogen and water vapor at high deuterium concentrations in application to the catalyst RKhTU-3SM. It is shown that the experimental rate constant of isotopic exchange for the pair protium – deuterium increases by almost a factor of two, while for exchange with tritium increasing the deuterium concentration from 5 to 95% does not change the experimentally observed rate constant to within the measurement error.

Atomic Energy. 2017;121(6):435-442
pages 435-442 views

Lutetium and Ytterbium Separation by Ion-Exchange Chromatography

Kosynkin V.D., Molchanova T.V., Zharova E.V.

Abstract

The results of separation the heavy rare-earth elements pair lutetium–ytterbium by ion-exchange chromatography are presented. The technological properties of modern absorbers of strong-sulfuric-acid cationites Purolite C160 and Cybber KX 100 are analyzed. The conditions for extracting lutetium with determination of the main factors – complex-forming substance, conditions of utilization, application of different moderators, elution rate, specific load, and others – are studied. It is shown that lutetium–ytterbium separation with production of fractions containing ≥99.9% Lu with concentration 1 g/liter and Yb concentration ≤0.5 mg/liter is possible in principle. A fraction with the maximum lutetium concentration 3.6–3.7 g/liter and ytterbium concentration 0.3–0.37 g/liter, corresponding to lutetium content 91–92%, was separated.

Atomic Energy. 2017;121(6):443-447
pages 443-447 views

Laser Beam Transmission by Inorganic Liquid Activated by Neodymium and Uranyl in Pulsed Excitation by Uranium Fission Fragments

D’yachenko P.P., Kulikov P.A., Seregina E.A., Seregin A.A., Tikhonov G.V.

Abstract

The transmission of 1.054 μm probing laser radiation by laser liquid \( {\mathrm{POCl}}_{3^{\hbox{--} }}{{\mathrm{SnCl}}_{4^{\hbox{--}}}}^{235}{\mathrm{UO}}_2^{2+}\hbox{--} {\mathrm{Nd}}^{3+} \) excited by uranium fission fragments was measured. It is shown that for liquid pressure 10.1 MPa the transmission of the liquid does not exceed 1. It is found that the transmission of the liquid in the active element with aperture 25 mm is approximately 4 times lower than in an element with aperture 10 mm. A qualitative explanation of the observed effect is proposed on the basis of the assumption that light was scattered by radial acoustic density waves in the liquid. This effect can serve as one of the primary reasons for the absence of lasing during nuclear pumping of the liquid under discussion. Methods of reducing the influence of this effect are examined.

Atomic Energy. 2017;121(6):448-455
pages 448-455 views