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Vol 38, No 6 (2016)

The New in Science About Water

Kinetics of formation of hydrogen peroxide in vacuum ultraviolet radiation of water

Goncharuk V.V., Dolenko S.A., Kravchenko A.M., Samsoni-Todorov A.O.

Abstract

The article shows the possibility of formation of hydrogen peroxide when treating samples of various types of water (high resistant, distilled and tap water) by vacuum ultraviolet radiation (λ = 185 nm). It has been found the impact of temperature, the pH and dissolved CO2 on the kinetics of formation of hydrogen peroxide in photolysis of water.

Journal of Water Chemistry and Technology. 2016;38(6):307-312
pages 307-312 views

Physical Chemistry of Water Treatment Processes

Impact of electrochemically active diaphragm on dehydration of finely dispersed precipitates

Lysenko L.L., Mishchuk N.A., Nesmeyanova T.A., Klishchenko R.E.

Abstract

The article has proposed a new method of intensification of the dehydration of clayey dispersion based on the use of an electrochemically active diaphragm. Analyzed was impact of a carbon diaphragm on the distribution of the field tension in a cell and the electroosmotic transport of the liquid at different pH of the porous solution. Optimal conditions for dehydration of a model dispersion have been determined.

Journal of Water Chemistry and Technology. 2016;38(6):313-318
pages 313-318 views

Kinetic and equilibrium studies of fluoride adsorption by a carbonaceous material from pyrolysis of waste sludge

Dogan V., Aydin S.

Abstract

The efficiency of the adsorption for fluoride by sludge from the treatment of starch industry wastewater was investigated. Batch experiments were conducted in order to determine the parameters that affect the adsorption process. The activation for waste sludge and specific surface area and porosity effects in enhancing the pyrolysis conditions were determined. The adsorption parameters of initial fluoride concentration, pH and adsorbent dosage were investigated with carbonaceous material. As a result of pyrolysis of samples treated with ZnCl2 1196 m2/g, the specific surface area was reached. Correlation coefficient of 0.99 and 12.75 mg/g adsorption capacity and adsorption isotherm model were revealed as convenient. Experimental results show that the adsorption of fluoride waste sludge will be effective in many ways in which the adsorbent is applied.

Journal of Water Chemistry and Technology. 2016;38(6):319-326
pages 319-326 views

Water Treatment and Demineralization Technology

The use of adsorption-active additions of some natural minerals for raising the quality of coagulation purification of natural water

Tarasevich Y.I., Trifonov M.Y., Ostapenko V.T., Kulishenko E., Kravchenko T.B.

Abstract

laboratory, pilot and production tests were carried out aimed at the use of powder clinoptilolite jointly with aluminum sulfate to improve the quality of purification of the Dnieper river water. The article showed the advantages of a combined use of these reagents: higher degree of purification, lower consumption of regents, and smaller volume of deposits. The research has begun to obtain composite coagulant by treating with hot sulfuric acid of clinoptilolite and aluminum hydroxide. First research has been conducted of water coagulation under laboratory conditions using composite coagulant and its efficiency was demonstrated.

Journal of Water Chemistry and Technology. 2016;38(6):327-330
pages 327-330 views

Obtaining of deep desalinated water by the electromembrane method using ion–exchange resins

Chebotareva R.D., Bashtan S.Y., Kakabaev R.I., Remez S.V.

Abstract

The article has investigated the process of water electrodeionization using ion–exchange resins KU-2 and AV-17 in the volume ratio 1: 1.4. It has been shown that at the location of the ion–exchange medium in chambers of the unit by separate layers one observes a higher efficiency of desalination; the specific electric resistance of diazolyte reaches 10.4 MΩ · cm.

Journal of Water Chemistry and Technology. 2016;38(6):331-335
pages 331-335 views

Liquid–phase extraction treatment of wastewater of paint and varnish production facilities in the extractor with mixer

Gasanov A.A., Suleimanov G.Z., Kelbaliev G.I.

Abstract

Liquid–phase extraction technology providing the maximum wastewater purification from such electrolyte composition components as butylglycol, phenylisopropanol, ascetic acid, and acetylacetone has been developed. A mathematical model of the process is proposed that takes into account the hydrodynamics of liquid flow and mass transfer in phases for each component. The differential cell model was used to determine the process parameters and calculate the basic dimensions of extractor. In addition, a three-stage process flowsheet with minimum extractant consumption was also presented.

Journal of Water Chemistry and Technology. 2016;38(6):336-341
pages 336-341 views

Possibility of improving technological effectiveness of dairy wastewater treatment through application of active fillings and microwave radiation

Zieliñski M., Dêbowski M., Krzemieniewski M., Brudniak A., Kisielewska M.

Abstract

The aim of the study was to determine the technological effectiveness of treatment process of model dairy wastewater in anaerobic reactors with active filling (AF), heated with electromagnetic microwave radiation (EMR). Experiments were conducted on a laboratory scale. The AF were produced using micro-pore extrusion technology. The study demonstrated that AF introduction to the technological system and application of EMR significantly improved the effectiveness of organic compounds, phosphorus removal and biogas production. Initial organic loading rate also affected the final results of wastewater treatment.

Journal of Water Chemistry and Technology. 2016;38(6):342-348
pages 342-348 views

Biological Methods of Water Treatment

Formation of a test system and the choice of test criteria when biotesting natural waters

Goncharuk V.V., Syroeshkin A.V., Kovalenko V.F., Zlatskiy I.A.

Abstract

Described are main problems of biotesting natural water. Defined are principles for formation of a test system and factors influencing it. Proposed are main areas for the choice of sensitive test reaction of organisms and test criteria for assessing the quality of natural water by the results of their biotesting.

Journal of Water Chemistry and Technology. 2016;38(6):349-352
pages 349-352 views

Natural Water

The influence of natural organic matter on trihalomethanes formation during the conditioning of drinking water

Klymenko N.A., Samsoni-Todorova E.A., Savchina L.A.

Abstract

The behavior pattern of the content of disinfection by-products in samples from the clean water reservoir of the Dnieper water supply plant as a function of the total organic carbon concentration, ultraviolet absorption at λ = 254 nm, and the specific ultraviolet absorption has been investigated. It was established that with due regard for specific peculiarities of the Dnieper water composition in different year seasons, the total organic carbon concentration was the most expedient for a potential-determining indicator of trihalomethanes formation.

Journal of Water Chemistry and Technology. 2016;38(6):353-357
pages 353-357 views

Assessment of groundwater quality and its suitability for agricultural usage in and around Rangampeta area, Andhra Pradesh, south India

Nagaraju A., Thejaswi A., Sharifi Z.

Abstract

The aim of this study is to assess the groundwater quality of Rangampeta area for irrigation and domestic purposes. The groundwater samples were analyzed for distribution of chemical elements Ca, Mg, Na, K, Si, HCO3, CO3, Cl and SO4. It also includes pH, electrical conductivity, total hardness, non carbonate hardness and total alkalinity. The parameters like sodium absorption ratio, adjusted sodium absorption ratio, sodium percentage, potential salinity, permeability index and residual sodium carbonate were calculated. The dominant hydrochemical facies of groundwater are Ca–Mg–Cl and Na–Cl Water Types. The Gibbs’s diagram plots suggest that the chemical weathering of rock forming minerals is the major driving force controlling water chemistry in this area. The positive chloro-alkaline indices revealed that the groundwater has suffered ion exchange between Na and K of water with Ca and Mg of soil during its flow.

Journal of Water Chemistry and Technology. 2016;38(6):358-365
pages 358-365 views

Current status of arsenic contamination in drinking water and treatment practice in some rural areas of West Bengal, India

Bhakta J.N., Rana S., Jana J., Bag S.K., Lahiri S., Jana B.B., Panning F., Fechter L.

Abstract

The aim of the present investigation was to draw the current scenario of arsenic (As) contamination in drinking water of community tube well and drinking water treated by tube wells installed with different adsorbent media-based treatment plants in districts Nadia, Hooghly and North 24-Parganas districts, West Bengal, India. As removal efficiencies of different treatment plants varied from 23 to 71%, which is largely governed by adsorption capacity of adsorbent and influencing environmental factors. Though investigated treatment plants removed substantial amount of As from tube well water, high As concentration in treated drinking water was retained after passing through the treatment plants. This high level of As concentration in tube well water and retention of high As concentration in treated drinking water were severe for the consumers which therefore, indicating the improvement of removal efficiency of treatment plant by meticulously considering favorable influencing factors or/and application of other high capacity treatment alternatives to adsorb the excess As retained in drinking water and regular monitoring of As concentration in the treated drinking water are indispensable.

Journal of Water Chemistry and Technology. 2016;38(6):366-373
pages 366-373 views