Email this article Synthesis and structure of a 2D Zn complex with mixed ligands stacked in offset ABAB manner
- Authors: Qin L.1,2, Wang Y.1,2, Ni G.1,2
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Affiliations:
- Department of chemical engineering and food processing, Xuancheng Campus
- Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering
- Issue: Vol 61, No 4 (2016)
- Pages: 616-619
- Section: Structure of Organic Compounds
- URL: https://journal-vniispk.ru/1063-7745/article/view/190172
- DOI: https://doi.org/10.1134/S1063774516040131
- ID: 190172
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Abstract
The title complex, {[Zn(ODIB)1/2(bpdc)]·2DMF}n was prepared under hydrothermal conditions (dimethylformamide and water) based on two ligands, namely, 1,1′-oxy-bis[3,5-diimidazolyl-benzene] (ODIB) and biphenyldicarboxylic acid (H2bpdc). ODIB ligands link Zn cations to give layers in crystal. bpdc2– anions coordinate to Zn atoms, however, their introduction does not increase the dimension of the structure. Each layer is partially passes through the adjacent layers in the offset ABAB manner.
About the authors
Ling Qin
Department of chemical engineering and food processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering
Author for correspondence.
Email: qinling0924013@163.com
China, Xuancheng, Anhui, 242000; Nanjing
Yan-Qing Wang
Department of chemical engineering and food processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering
Email: qinling0924013@163.com
China, Xuancheng, Anhui, 242000; Nanjing
Gang Ni
Department of chemical engineering and food processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering
Email: qinling0924013@163.com
China, Xuancheng, Anhui, 242000; Nanjing
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