Catalytic epitaxy of ZnO whiskers via the vapor–crystal mechanism


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Abstract

A model of oriented growth of (0001) ZnO whiskers on sapphire substrates via the vapor–crystal mechanism using the catalytic properties of gold islands is proposed. The morphological transition from the primary pyramidal ZnO structures to hexagonal ZnO whiskers is described in terms of the minimization of the free energy density of three-dimensional heteroepitaxial islands.

About the authors

A. E. Muslimov

Shubnikov Institute of Crystallography, Federal Research Centre “Crystallography and Photonics”

Email: amuslimov@mail.ru
Russian Federation, Moscow, 119333

A. V. Butashin

Shubnikov Institute of Crystallography, Federal Research Centre “Crystallography and Photonics”

Email: amuslimov@mail.ru
Russian Federation, Moscow, 119333

V. M. Kanevsky

Shubnikov Institute of Crystallography, Federal Research Centre “Crystallography and Photonics”

Email: amuslimov@mail.ru
Russian Federation, Moscow, 119333

V. A. Babaev

Dagestan State University

Email: amuslimov@mail.ru
Russian Federation, Makhachkala, 367000

A. M. Ismailov

Dagestan State University

Author for correspondence.
Email: amuslimov@mail.ru
Russian Federation, Makhachkala, 367000

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