Email this article Synthesis, Structure, and Fluorescence of a Novel Cadmium Compound
- Authors: Yao Z.1, Chen W.2,3
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Affiliations:
- Biology and Chemistry Engineering Department
- Institute of Applied Chemistry, School of Chemistry and Chemical Engineering
- State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter
- Issue: Vol 62, No 7 (2017)
- Pages: 1017-1021
- Section: Structure of Inorganic Compounds
- URL: https://journal-vniispk.ru/1063-7745/article/view/191600
- DOI: https://doi.org/10.1134/S1063774517070355
- ID: 191600
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Abstract
A novel cadmium compound, [(CdI3)2(μ2-I)]2(Me2-4,4'-H2bipy)3 (1) (Me = methyl; 4,4'-bipy = 4,4'-bipyridine) with the Me2-4,4'-H2bipy moiety generated in situ, has been prepared through a solvothermal reaction and structurally characterized by X-ray single crystal diffraction analysis. Compound 1 is characterized by an isolated structural motif, consisting of [(CdI3)2(μ2-I)]3– anions and Me2-4,4'-H2bipy2+ cations. The [(CdI3)2(μ2-I)]3– anions and Me2-4,4'-H2bipy2+ cations interconnect together via C–H···I hydrogen-bonding interactions to complete a three-dimensional (3D) supramolecular network. Solid state fluorescent spectrum reveals an emission band in the violet region.
About the authors
Zhong-Liang Yao
Biology and Chemistry Engineering Department
Email: wtchen@jgsu.edu.cn
China, Fuqing, Fujian, 350300
Wen-Tong Chen
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter
Author for correspondence.
Email: wtchen@jgsu.edu.cn
China, Ji’an, Jiangxi, 343009; Fuzhou, Fujian, 350002
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