Email this article The First Seven-Coordinated Triiodo Complex of Rhenium(III)
- Authors: Schoultz X.1, Gerber T.I.1, Betz R.1, Hosten E.C.1
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Affiliations:
- Department of Chemistry
- Issue: Vol 62, No 7 (2017)
- Pages: 1135-1137
- Section: Structure of Organic Compounds
- URL: https://journal-vniispk.ru/1063-7745/article/view/191903
- DOI: https://doi.org/10.1134/S1063774517070239
- ID: 191903
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Abstract
The reaction of cis-[ReO2I(PPh3)2] with tert-butyl isocyanide in benzene led to the isolation of the complex [ReI3(CN-t-Bu)3(PPh3)] (1). The complex is unusual since it contains bulky ligands with large cone angles, i.e. three iodides, three isocyanides with tert-butyl groups and a triphenylphosphine as ligands in a seven-coordinate geometry around the rhenium(III) metal ion.
About the authors
X. Schoultz
Department of Chemistry
Email: thomas.gerber@nmmu.ac.za
South Africa, Port Elizabeth
T. I. A. Gerber
Department of Chemistry
Author for correspondence.
Email: thomas.gerber@nmmu.ac.za
South Africa, Port Elizabeth
R. Betz
Department of Chemistry
Email: thomas.gerber@nmmu.ac.za
South Africa, Port Elizabeth
E. C. Hosten
Department of Chemistry
Email: thomas.gerber@nmmu.ac.za
South Africa, Port Elizabeth
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