Email this article Ligands Entrapment in a 2D Parallel Stacked Co Complex with Mixed Ligands
- Authors: Qin L.1,2, Liu Q.1, Yang X.1, Wang Y.1
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Affiliations:
- Department of Chemical Engineering and Food Processing, Xuancheng Campus
- Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering
- Issue: Vol 62, No 7 (2017)
- Pages: 1177-1181
- Section: Structure of Macromolecular Compounds
- URL: https://journal-vniispk.ru/1063-7745/article/view/192138
- DOI: https://doi.org/10.1134/S106377451707015X
- ID: 192138
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Abstract
The title complex, {[Co4(DPT)4(bdc)4] · DPT · DMF · H2O}n (1) was prepared under hydrothermal condition (dimethylformamide and water) based on mixed ligands, namely, 2,5-dipyridinethiophene (DPT) and 1,4-benzenedicarboxylate (H2bdc). DPT and bdc2– ligands link Co cations to give a 2D layer in the title complex. Each layer is stacked in parallel manners. The title compound has channels running in parallel to the a axis with the dimensions of 3.6 × 6.8 Å2, which entraps a guest DPT ligand molecule.
About the authors
Ling Qin
Department of Chemical Engineering and Food Processing, Xuancheng Campus; Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering
Author for correspondence.
Email: qinling0924013@163.com
China, Xuancheng, Anhui, 242000; Nanjing, Jiangsu
Qing-He Liu
Department of Chemical Engineering and Food Processing, Xuancheng Campus
Email: qinling0924013@163.com
China, Xuancheng, Anhui, 242000
Xi Yang
Department of Chemical Engineering and Food Processing, Xuancheng Campus
Email: qinling0924013@163.com
China, Xuancheng, Anhui, 242000
Yan-Qing Wang
Department of Chemical Engineering and Food Processing, Xuancheng Campus
Email: qinling0924013@163.com
China, Xuancheng, Anhui, 242000
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