Morphological Stability of the Solid–Liquid Interface during Melt Crystallization of Ca1–xSrxF2 Solid Solution


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Abstract

Proceeding from the phase diagram of the CaF2–SrF2 system, the stability of crystal–melt interface of solid solution against constitutional supercooling has been calculated. When comparing the stability function F(x) calculated curve with the results of single crystals growing by the Bridgman method, the interdiffusion coefficient of cations in melt was estimated to be D > 2.4 × 10–4 cm2/s.

About the authors

P. P. Fedorov

Prokhorov General Physics Institute of the Russian Academy of Sciences; Ogarev Mordovia State University

Author for correspondence.
Email: ppfedorov@yandex.ru
Russian Federation, Moscow, 119991; Saransk, 430000

S. N. Ushakov

Ogarev Mordovia State University

Email: ppfedorov@yandex.ru
Russian Federation, Saransk, 430000

M. A. Uslamina

Ogarev Mordovia State University

Email: ppfedorov@yandex.ru
Russian Federation, Saransk, 430000

E. V. Chernova

Prokhorov General Physics Institute of the Russian Academy of Sciences

Email: ppfedorov@yandex.ru
Russian Federation, Moscow, 119991

S. V. Kuznetsov

Prokhorov General Physics Institute of the Russian Academy of Sciences

Email: ppfedorov@yandex.ru
Russian Federation, Moscow, 119991

V. V. Voronov

Prokhorov General Physics Institute of the Russian Academy of Sciences

Email: ppfedorov@yandex.ru
Russian Federation, Moscow, 119991

A. Düvel

Institute of Physical Chemistry and Electrochemistry; School of Physical Sciences

Email: ppfedorov@yandex.ru
Germany, Callinstr. 3-3a, Hannover, 30167; Canterbury, Kent, CT2 7NH

P. Heitjans

Institute of Physical Chemistry and Electrochemistry

Email: ppfedorov@yandex.ru
Germany, Callinstr. 3-3a, Hannover, 30167

A. A. Pynenkov

Ogarev Mordovia State University

Email: ppfedorov@yandex.ru
Russian Federation, Saransk, 430000

K. N. Nishchev

Ogarev Mordovia State University

Email: ppfedorov@yandex.ru
Russian Federation, Saransk, 430000

V. V. Osiko

Prokhorov General Physics Institute of the Russian Academy of Sciences

Email: ppfedorov@yandex.ru
Russian Federation, Moscow, 119991

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