Email this article Skeletal Sublattices of Heavy Components As a Basis of Stability of Crystal Structures
- Authors: Borisov S.V.1, Magarill S.A.1, Pervukhina N.V.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 64, No 1 (2019)
- Pages: 30-35
- Section: Theory of Crystal Structures
- URL: https://journal-vniispk.ru/1063-7745/article/view/193559
- DOI: https://doi.org/10.1134/S1063774519010036
- ID: 193559
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Abstract
A crystallographic structural analysis of low- and high-temperature phases of BaSi2O5 and Na3SO4F compounds has been carried out in order to confirm the thesis that the stability of natural-abundant structural types is mainly determined by the configuration of the heaviest components. The geometry of cation (skeletal) sublattices is presented; it is shown that they play a key role in the formation of structures and are relatively stable at temperature phase transitions.
About the authors
S. V. Borisov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk, 630090
S. A. Magarill
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk, 630090
N. V. Pervukhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
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