Email this article Production of Complex Hydrosulphates in the K3H(SO4)2–Rb3H(SO4)2 Series: Part I
- Authors: Komornikov V.A.1, Grebenev V.V.1, Timakov I.S.1, Ksenofontov D.A.2, Andreev P.V.3, Makarova I.P.1, Selezneva E.V.1
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Affiliations:
- Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences
- Moscow State University
- Lobachevsky State University of Nizhny Novgorod
- Issue: Vol 64, No 3 (2019)
- Pages: 479-483
- Section: Crystal Growth
- URL: https://journal-vniispk.ru/1063-7745/article/view/194012
- DOI: https://doi.org/10.1134/S1063774519030143
- ID: 194012
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Abstract
The phase equilibria in the K3H(SO4)2–Rb3H(SO4)2–H2O cross section have been investigated under isothermal conditions at 25°C. The concentration limits of crystallization of solid solutions with the general formulas (Rb1 – xKx)3H(SO4)2 and (Rb1 – xKx)2SO4 are determined. The dependences of the equilibria of saturated solution on the initial production conditions are revealed. The growth conditions for large single crystals of complex acid rubidium–potassium sulfates are determined.
About the authors
V. A. Komornikov
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences
Author for correspondence.
Email: v.a.kom@mail.ru
Russian Federation, Moscow, 119333
V. V. Grebenev
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences
Email: v.a.kom@mail.ru
Russian Federation, Moscow, 119333
I. S. Timakov
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences
Email: v.a.kom@mail.ru
Russian Federation, Moscow, 119333
D. A. Ksenofontov
Moscow State University
Email: v.a.kom@mail.ru
Russian Federation, Moscow
P. V. Andreev
Lobachevsky State University of Nizhny Novgorod
Email: v.a.kom@mail.ru
Russian Federation, Nizhny Novgorod, 603950
I. P. Makarova
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences
Email: v.a.kom@mail.ru
Russian Federation, Moscow, 119333
E. V. Selezneva
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”Russian Academy of Sciences
Email: v.a.kom@mail.ru
Russian Federation, Moscow, 119333
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