On the Crystallographic Polytypes SrAl12O19 (BaFe12O19)–BaFe18O27
- Authors: Borisov S.V.1, Magarill S.A.1, Pervukhina N.V.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 64, No 4 (2019)
- Pages: 566-569
- Section: Theory of Crystal Structures
- URL: https://journal-vniispk.ru/1063-7745/article/view/194064
- DOI: https://doi.org/10.1134/S1063774519040060
- ID: 194064
Cite item
Abstract
A crystallographic analysis of SrAl12O19 (isostructural to BaFe12O19) and BaFe18O27 showed that the structures of both polytypes contain almost identical cationic and anionic (with participation of a large cation) sublattices, whose geometry is consistent with the high symmetry P63/mmc of these compounds. The presence of unified “skeletal” sublattices is considered to be the main condition for the formation of polytype structures.
About the authors
S. V. Borisov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk, 630090
S. A. Magarill
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk, 630090
N. V. Pervukhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
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