Vol 50, No 6 (2017)

Soils of the Summer Garden—the first regular (French-style) garden in Russia—are characterized on the basis of the materials of field study performed during reconstruction of the garden in 2005–2011. Most of these soils are filled soils—urbostratozems—underlain by the loamy sands deposited in the Littorina Sea or by the buried gray-humus gleyic and gleyed soils. Urbostratozems are characterized by the slightly acid reaction in the topsoil horizons and slightly alkaline reaction in the middle-profile and lower horizons. The humus content in them varies from 0.2 to 6.8%; in the buried gray-humus soils, it is within 1.3–2.6%. The soils of the garden are characterized by the high and extremely high content of available phosphorus and the predominantly low content of available potassium as determined by Machigin’s method. The bulk content of Pb in the surface soil horizons during the period of our study exceeded the maximum permissible concentration by 3–20 times; the bulk contents of Cu and Zn exceeded the tentative permissible concentrations for coarse-textured soils by 2–6 and 4–20 times, respectively. The main sources of the soil contamination by the heavy metals are the nearby highways. Local contaminated area was also found near the household yard.

The profile distributions of oxalate- and pyrophosphate-soluble Al compounds and oxalate-soluble Si compounds in the main horizons of pale-podzolic soils of the Central Forest Reserve and the fractions <1. 1–5, and >5 μm have been considered. In the clay-eluvial part of soil profile, the content of these compounds is differentiated by the eluvial–illuvial type with a clear accumulation in the EL horizon compared to the AEL horizon. This distribution is largely ensured by their differentiation in the clay and fine silt fractions, while an accumulative distribution of mobile Al compounds is observed in fractions >5 μm. The high correlation between the Al and Si contents in the Tamm extracts from the clay and fine silt fractions with the (Al_ox–Al_py)/Si_ox molar ratios, which are in the range of 1–3 in the EL horizon, confirms that mobile compounds are accumulated in these fractions in the form of amorphous aluminosilicates. In the AEL and EL horizons, an additional amount of Al can pass into the oxalate solution from the fine fractions due to the dissolution of Al hydroxide interlayers of soil chlorites. The eluvial–illuvial distribution of mobile Al and Si compounds typical for Al–Fe–humus podzols within the clay-illuvial part of profiles of the soils under study can be considered as an example of superimposed evolution.

Mineralization kinetics of corn and clover residues in quartz sand, loam, sand + 15% bentonite, and sand + 30% kaolinite have been studied. A scheme has been proposed for the transformation of plant residues in mineral substrates. Kinetic parameters of mineralization have been calculated with the use of a first-order two-term exponential polynomial. It has been shown that the share of labile organic carbon pool in the clover biomass is higher (57–63%) than in the corn biomass (47–49%), which is related to the biochemical composition of plant residues. The mineralization constants of clover residues generally significantly exceed those of corn because of the stronger stabilization of the decomposition products of corn residues. The turnover time of the labile clover pool (4–9 days) in all substrates and that of the labile corn pool (8–10 days) in sands and substrates containing kaolinites and bentonite are typical for organic acids, amino acids, and simple sugars. In the loamy substrate, the turnover time of labile corn pool is about 46 days due to the stronger stabilization of components of the labile pool containing large amounts of organic acids. The turnover time of the stable clover pool (0.95 years) is significantly lower than that of the stable corn pool (1.60 years) and largely corresponds to the turnover time of plant biomass.

Soil sequences along catenas crossing the peripheral parts of shallow-water drying lakes in the south of Siberia have been studied. They include the sulfidic and typical playa (sor) solonchaks (Gleyic Solonchaks), playa solonchak over the buried solonetz (Gleyic Solonchak Thapto-Solonetz)), shallow solonetz–solonchak (Salic Solonetz), and solonetzic and solonchakous chernozemic-meadow soil (Luvic Gleyic Chernozem (Sodic, Salic)). This spatial sequence also represents a series of historical stages of the development of halomorphic soils: the amphibian, hydromorphic, semihydromorphic, and automorphic–paleohydromorphic stages. During all of them, the biogenic component plays a significant role in the matter budget of halomorphic soils. The diversity, number, and functional activity of large insects and spiders are particularly important. Their total abundance in the course of transformation of the halomorphic soils decreases from several thousand to about 100 specimens/(m² day), whereas their species diversity increases from 17 to 45 species. Changes in the functional structure of the soil zoocenosis and its impact on the character and intensity of pedogenetic processes can be considered driving forces of the transformation of hydromorphic soils. This is ensured by the sequential alteration of the groups of invertebrates with different types of cenotic strategy and different mechanisms of adaptation to biotic and abiotic components of the soil in the course of the development of the soil zoocenosis.

Urban soils (Urbic Technosols) formed within or near the industrial sites removed of service show a considerable excess over the regional background in the content of Pb, Zn, Cu, Mn, Cr, Ni, as well as over the average content of W, Mo, Pb, Sb, Cr, Cu, Sn, Ni, Zn, and Mn in urban soils. Microelements are concentrated for the most part in the soil fine earth, and above all, in the fraction with particle size <0.1 mm. Surface films (on quartz and feldspar grains) of quartz–feldspar–muscovite (partially with tremolite and chlorite) composition and undifferentiated dispersed mixture of quartz, albite, microcline, muscovite and organomineral soil substance are the strongest concentrators of heavy metals and metalloids. Pb and Sn are partially present in soils as oxides, and a part of Zn and Pb, in the form of substantial admixtures to technogenic chemical compounds. As a whole, distribution of elements in the studied soils is controlled by the specifics and type of contamination, resistance of coarser grains to weathering under the given physicochemical conditions, and by predominantly mineral (quartz–feldspar) composition of the solids in soil layers and the features of elements proper.

The results of long-term studies of the contents of bulk forms of metals (Cu, Zn, Fe, Ni, Pb, Mn, Co, and Cd) and their mobile compounds in soils of background and human-disturbed areas within the Krasnoural’sk–Sibai–Gai copper–zinc and Baimak–Buribai mixed copper mineralization zones in the Bashkir Transural region are discussed. It is shown that soils of the region are characterized by abnormally high natural total contents of heavy metals (HMs) typomorphic for ore mineralization: Cu, Zn, and Fe for the Sibai province and Cu, Zn, and Ni for the Baimak province. In the case of a shallow depth of the ores, the concentrations of HMs in the soils are close to or higher than the tentative permissible concentration values. The concentrations of mobile HM compounds in soils of background areas and their percentage in the total HM content strongly vary from year to year in dependence on weather conditions, position in the soil catenas, species composition of vegetation, and distance from the source of technogenic contamination. The high natural variability in the content of mobile HM compounds in soils complicates the reliable determination of the regional geochemical background and necessitates annual estimation of background parameters for the purposes of the ecological monitoring of soils. The bulk content of Cu and Zn content in soils near mining enterprises exceeds the regional geochemical background values by 2–12 times and the tentative permissible concentrations of these metals by 2–4 times. Anthropogenic contamination results in a sharp rise in the content of mobile HM compounds in soils. Their highest concentrations exceed the maximum permissible concentrations by 26 times for Cu, 18 times for Zn, and 2 times for Pb. Soil contamination in the impact zone of mining enterprises is extremely dangerous or dangerous. However, because of the high temporal variability in the migration and accumulation of HMs in the soils, the recent decline in the ore mining activities, and the construction of purification facilities, no definite temporal trends in the contents of HMs in the soils have been found in the studied region for the period from 1998 to 2015.

The purpose of this study was to analyze the influence of wind erosion on the productivity of citric crops over gypsiric Fluvisols in Gador area (Almeria, SE Spain) by blowing air through a wind tunnel. Wind erosion varies considerably depending on time since the last tillage. This is because a physical crust forms after tilling which protects the soil from wind. Crust formation in the study area is strongly favored by dew, which causes them to form in around a week. The repeated measurements ANOVA, as a nonparametric alternative to the ANOVA, using the Geiiser method and the Friedman test shows significant differences (P ≤ 0.05) in the fractions of very fine sand and coarse silt, which confirmed that very fine sand and coarse silt are the fractions most susceptible to loss from wind. The same statistical analysis for fertility showed smaller differences in organic carbon and K₂O content, while N and P₂O₅ increased. Nutrients lost from wind imply an additional fertilization cost for a crop to be economically feasible. The cost of this restoration of nutrients lost from the soil because of wind erosion was based on experimental data taken in crusted soil and immediately after tilling. Losses in organic matter (O.M.), N, P₂O₅ and K₂O were estimated based on the cost of fertilizers most commonly used in the area.