Vol 50, No 9 (2017)

The results of a hierarchical morphogenetic, physicochemical, and mineralogical study of the Ryshkovo full-profile texture-differentiated paleosol of the Mikulino Interglacial from the section at Aleksandrov quarry in Kursk oblast are discussed. The correlation analysis of the stratigraphy of this section with global geological records made it possible to determine the position of the Ryshkovo paleosol in the chronostratigraphic system of the Late Pleistocene and to attribute it to stage MIS 5e; the duration of pedogenesis for this paleosol was no more than 12–15 ka. The results of the study indicate that the Ryshkovo paleosol is close in its properties to the Holocene soddy-podzolic soils of the East European Plain. No direct evidences in favor of the former interpretation of this paleosol as a lessivated soil genetically close to Luvisols of nemoral broadleaved forest of Central Europe have been found. The difference between the paleosol of the Mikulino Interglacial and the modern soddy-podzolic soils is mainly related to the distribution of clay coatings. In the upper part of the illuvial horizon of Mikulino paleosol, clay coatings are few in number, and typical tongues of podzolized (albic) material are absent in the profile. At the same time, silty coatings (skeletans) are abundant even in the lower part of the illuvial horizon. In general, the Mikulino paleosol is characterized by a smaller diversity of clay pedofeatures. These differences might be related to less contrasting fluctuations of the environmental conditions in the second half of the Mikulino Interglacial, to the periodical renewal of the eluvial part of Mikulino paleosol by erosional and accumulative processes, and to the absence of anthropogenic impacts on the soil during the Mikulino Interglacial. The burying of the Ryshkovo paleosol took place due to the intense development of erosional processes induced by the contrasting climatic events at the end of the interglacial period accompanied by catastrophic forest fires and sharp cooling of the climate upon the transition to the Valdai glaciation.

Polyacrylamide gel electrophoresis in combination with size-exclusion chromatography (SEC–PAGE) has been used to obtain stable electrophoretic fractions of different molecular size (MS) from chernozem humic acids (HAs). Three-dimensional fluorescence charts of chernozem HAs and their fractions have been obtained for the first time, and all fluorescence excitation–emission maxima have been identified in the excitation wavelength range of 250–500 nm. It has been found that fractionation by the SEC–PAGE method results in a nonuniform distribution of protein- and humin-like fluorescence of the original HA preparation among the electrophoretic fractions. The electrophoretic fractions of the highest and medium MSs have only the main protein-like fluorescence maximum and traces of humin-like fluorescence. In the electrophoretic fraction of the lowest MS, the intensity of protein-like fluorescence is low, but the major part of humin-like fluorescence is localized there. Relationships between the intensity of protein-like fluorescence and the weight distribution of amino acids have been revealed, as well as between the degree of aromaticity and the intensity of humin-like fluorescence in electrophoretic fractions of different MSs. The obtained relationships can be useful in the interpretation of the spatial structural organization and ecological functions of soil HAs.

Natural and anthropogenic factors determining the distribution and accumulation features of Pb, Cu, Zn, Cr, Ni, Cd, Mn, and As in the soil–plant system of the Don River estuary and the northern and southern Russian coasts of Taganrog Bay estuary have been studied. High mobility of Cu, Zn, Pb, and Cd has been revealed in alluvial soils. This is confirmed by the significant bioavailability of Cu, Zn, and, to a lesser degree, Cd and the technophily of Pb, which are accumulated in tissues of macrophytic plants. Statistically significant positive correlations have been found between the mobile forms of Cu, Zn, Cd, and Mn in the soil and the accumulation of metals in plants. Impact zones with increased metal contents in aquatic ecosystems can be revealed by bioindication from the morphofunctional parameters of macrophytic plants (with Typha L. as an example).

The emission of carbon dioxide (CO₂) from podzols (Albic Podzols (Arenic)) and the factors controlling its spatiotemporal variability in the forest ecosystems of the Pasvik Reserve in the Kola Subarctic are characterized. Relatively favorable climatic conditions beyond the polar circle in summer are responsible for intensive soil respiration. The type of forest affects the emission of CO₂ from the soil surface. The lowest rate of the CO₂ emission is typical of the soils under lichen pine forest (105–220 mg C/(m² h) or 180 g C/m² during the summertime). Higher rates are observed for the soils under green moss pine (170–385 mg C/(m² h) or 360 g C/m² during the summertime) and birch (190–410 mg C/(m² h) or 470 g C/m² during the summertime) forests. This may related to a higher contribution of root respiration (44, 88, and 67%, respectively). Soil respiration and the contribution of root respiration to it increase with an increase in the canopy density; mass of small roots; microbial biomass; depth of the stony layer; soil moistening; and the contents of available carbon, nitrogen, phosphorus, and potassium compounds. At the same time, they decrease with an increase in the portion of lichens in the ground cover. The seasonal dynamics are characterized by the CO₂ emission maximums in the summer and fall and minimum in the spring. The daily dynamics are smoothed under conditions of the polar day.

Soil hydraulic properties play a crucial role in simulating water flow and contaminant transport. Soil hydraulic properties are commonly measured using homogenized soil samples. However, soil structure has a significant effect on the soil ability to retain and to conduct water, particularly in aggregated soils. In order to determine the effect of soil homogenization on soil hydraulic properties and soil water transport, undisturbed soil samples were carefully collected. Five different soil structures were identified: Angular-blocky, Crumble, Angular-blocky (different soil texture), Granular, and subangular-blocky. The soil hydraulic properties were determined for undisturbed and homogenized soil samples for each soil structure. The soil hydraulic properties were used to model soil water transport using HYDRUS-1D.The homogenized soil samples showed a significant increase in wide pores (wCP) and a decrease in narrow pores (nCP). The wCP increased by 95.6, 141.2, 391.6, 3.9, 261.3%, and nCP decreased by 69.5, 10.5, 33.8, 72.7, and 39.3% for homogenized soil samples compared to undisturbed soil samples. The soil water retention curves exhibited a significant decrease in water holding capacity for homogenized soil samples compared with the undisturbed soil samples. The homogenized soil samples showed also a decrease in soil hydraulic conductivity. The simulated results showed that water movement and distribution were affected by soil homogenizing. Moreover, soil homogenizing affected soil hydraulic properties and soil water transport. However, field studies are being needed to find the effect of these differences on water, chemical, and pollutant transport under several scenarios.

The method of luminescent microscopy has been applied to study the structure of the microbial biomass of soils and soil-like bodies in East (the Thala Hills and Larsemann Hills oases) and West (Cape Burks, Hobbs coast) Antarctica. According to Soil Taxonomy, the studied soils mainly belong to the subgroups of Aquic Haploturbels, Typic Haploturbels, Typic Haplorthels, and Lithic Haplorthels. The major contribution to their microbial biomass belongs to fungi. The highest fungal biomass (up to 790 μg C/g soil) has been found in the soils with surface organic horizons in the form of thin moss/lichen litters, in which the development of fungal mycelium is most active. A larger part of fungal biomass (70–98%) is represented by spores. For the soils without vegetation cover, the accumulation of bacterial and fungal biomass takes place in the horizons under surface desert pavements. In the upper parts of the soils without vegetation cover and in the organic soil horizons, the major part (>60%) of fungal mycelium contains protective melanin pigments. Among bacteria, the high portion (up to 50%) of small filtering forms is observed. A considerable increase (up to 290.2 ± 27 μg C/g soil) in the fungal biomass owing to the development of yeasts has been shown for gley soils (gleyzems) developing from sapropel sediments under subaquatic conditions and for the algal–bacterial mat on the bottom of the lake (920.7 ± 46 μg C/g soil). The production of carbon dioxide by the soils varies from 0.47 to 2.34 μg C–CO₂/(g day). The intensity of nitrogen fixation in the studied samples is generally low: from 0.08 to 55.85 ng С₂Н₄/(g day). The intensity of denitrification varies from 0.09 to 19.28 μg N–N₂O/(g day).

The effect of rainfall intensity on the erosion of residual calcareous agrogray soils and clay-illuvial agrochernozems in the Southern Cis-Ural region on slopes of different inclination and vegetation type has been studied by simulating with a small-size sprinkler. It has been shown that soil loss linearly depends on rainfall intensity (2, 4, and 6 mm/min) and slope inclination (3° and 7°). When the rainfall intensity and duration, and the slope inclination increase, soil loss by erosion from agrogray soils increases higher than from agrochernozems. On the plowland with a slope of 3°, runoff begins 12, 10, and 5 min, on the average, after the beginning of rains at these intensities. When the slope increases to 7°, runoff begins earlier by 7, 6, and 4 min, respectively. After the beginning of runoff and with its increase by 1 mm, the soil loss from slopes of 3° and 7° reaches 4.2 and 25.7 t/ha on agrogray soils and 1.4 and 4.7 t/ha on agrochernozems, respectively. Fallow soils have higher erosion resistance, and the soil loss little depends on the slope gradient: it gradually increases to 0.3–1.0 t/ha per 1 mm of runoff with increasing rainfall intensity and duration. The content of physical clay in eroded material is higher than in the original soils. Fine fractions prevail in this material, which increases their humus content. The increase in rainfall intensity and duration to 4 and 6 mm/min results in the entrapment of coarse silt and sand by runoff.