Reaction of N-cyclohexyl-2-(2-hydroxynaphthalen-1-yl)pyrrolidine-1-carboxamide with resorcinol and its derivatives and synthesis of polyphenols
- Authors: Smolobochkin A.V.1, Gazizov A.S.1, Burilov A.R.1, Pudovik M.A.1
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Affiliations:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Issue: Vol 65, No 5 (2016)
- Pages: 1377-1379
- Section: Brief Communications
- URL: https://journal-vniispk.ru/1066-5285/article/view/238354
- DOI: https://doi.org/10.1007/s11172-016-1465-1
- ID: 238354
Cite item
Abstract
An acid-catalyzed pyrrolidine ring opening in 2-(2-hydroxynaphthalen-1-yl)pyrrolidine-1-carboxamides in the presence of resorcinols furnished new calix[4]resorcinols or 1,1-diarylbutanes modified with urea fragments. The process follows the retro-Mannich reaction mechanism, with the 2-naphthol fragment playing the role of the leaving group.
About the authors
A. V. Smolobochkin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: agazizov@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
A. S. Gazizov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Author for correspondence.
Email: agazizov@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
A. R. Burilov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: agazizov@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
M. A. Pudovik
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: agazizov@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
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