Email this article Structure control of heterometallic Li2Co2 metal core in pivalate clusters by varying apical ligands
- Authors: Sidorov A.A.1, Kiskin M.A.1, Aleksandrov G.G.1, Eremenko I.L.1
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Affiliations:
- N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Issue: Vol 65, No 11 (2016)
- Pages: 2754-2756
- Section: Brief Communications
- URL: https://journal-vniispk.ru/1066-5285/article/view/239463
- DOI: https://doi.org/10.1007/s11172-016-1647-x
- ID: 239463
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Abstract
Based on the heterometallic fragment {Li2Co2(Piv)6}, a new complex [(terpy)2Li2Co2(Piv)6] (1) was obtained, in which the terminal cobalt atoms coordinate the 2,2’:6’,2″-terpyridine (terpy) molecules. The metal core of the molecule is a Co—Li—Li—Co chain, the metal atoms in which are bonded between each other by the pairs of carboxylate bridges.
About the authors
A. A. Sidorov
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
M. A. Kiskin
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: mkiskin@igic.ras.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
G. G. Aleksandrov
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
I. L. Eremenko
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, 31 Leninsky prosp., Moscow, 119991
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