Electronic structure of europium( iii ) acrylate and methacrylate: an X-ray photoelectron spectroscopy and quantum chemical study

V. V. Korochentsev; E. V. Mikhailenko; A. V. Shurygin; V. I. Vovna; I. S. Os’mushko; A. G. Mirochnik; N. V. Petrochenkova

doi:10.1007/s11172-017-1984-4

Electronic structure of europium(iii) acrylate and methacrylate: an X-ray photoelectron spectroscopy and quantum chemical study

Authors: Korochentsev V.V.¹, Mikhailenko E.V.¹, Shurygin A.V.¹, Vovna V.I.¹, Os’mushko I.S.¹, Mirochnik A.G.², Petrochenkova N.V.²
Affiliations:
1. Far Eastern Federal University
2. Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences
Issue: Vol 66, No 11 (2017)
Pages: 2081-2089
Section: Full Article
URL: https://journal-vniispk.ru/1066-5285/article/view/241547
DOI: https://doi.org/10.1007/s11172-017-1984-4
ID: 241547

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Abstract

The electronic structure and specific features of the nature of chemical bonding in europium acrylate and europium methacrylate were investigated by X-ray photoelectron spectroscopy (XPS) and quantum chemistry methods. The effect of the replacement of acrylic acid by methacrylic acid was also studied. The assignment of bands in the valence region XPS spectra is proposed.