Three-dimensional copper(II) carboxylates based on 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid)
- Авторы: Zavakhina M.S.1,2, Samsonenko D.G.1,2, Dybtsev D.N.1,2, Fedin V.P.1,2
-
Учреждения:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Выпуск: Том 67, № 1 (2018)
- Страницы: 36-44
- Раздел: Article
- URL: https://journal-vniispk.ru/1066-5285/article/view/241898
- DOI: https://doi.org/10.1007/s11172-018-2034-6
- ID: 241898
Цитировать
Аннотация
The homochiral coordination polymers [Cu4(CH3OH)(H2O)4(Hbtb)(S-mal)2]•4H2O and [Cu4(CH3OH)(H2O)4(Hbtb)(R-mal)2]•4H2O were synthesized by heating S- or R-malic acid (H3mal), 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid) (H3btb), and copper(II) acetate in an aqueous methanolic solution. The reaction with copper(II) nitrate in aqueous dioxane afforded the coordination framework [Cu6(C4H8O2)3(H2O)3(btb)4]•4C4H8O2•10H2O, which does not contain chiral ligands. The compositions and crystal structures of the new compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric and elemental analysis.
Ключевые слова
Об авторах
M. Zavakhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
D. Samsonenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
D. Dybtsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Автор, ответственный за переписку.
Email: cluster@niic.nsc.ru
Россия, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
Дополнительные файлы
