Email this article Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system
- Authors: Rozentsvet V.A.1, Kozlov V.G.1, Sablina N.A.1, Stotskaya O.A.1
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Affiliations:
- Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
- Issue: Vol 67, No 8 (2018)
- Pages: 1419-1425
- Section: Article
- URL: https://journal-vniispk.ru/1066-5285/article/view/242809
- DOI: https://doi.org/10.1007/s11172-018-2234-0
- ID: 242809
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Abstract
Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system allows one to synthesize with high rates and yield fully soluble polybutadiene with controlled molecular characteristics. It was shown that the obtained cationic polybuta diene is characterized by predominantly 1,4-trans-structure and reduced unsaturation. The macromolecules of the cationic polybutadiene contain the initial tert-butyl and end chlorine-containing units.
About the authors
V. A. Rozentsvet
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Author for correspondence.
Email: rozentsvet@mail.ru
Russian Federation, 10 ul. Komzina, Tol’yatti, 445003
V. G. Kozlov
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Russian Federation, 10 ul. Komzina, Tol’yatti, 445003
N. A. Sablina
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Russian Federation, 10 ul. Komzina, Tol’yatti, 445003
O. A. Stotskaya
Institute of Ecology of the Volga River Basin, Russian Academy of Sciences
Email: rozentsvet@mail.ru
Russian Federation, 10 ul. Komzina, Tol’yatti, 445003
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