A new method for the preparation of 1-(chloromethyl)- and 1-(dichloromethyl)silatranes


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Abstract

A preparative method for the synthesis of 1-(chloromethyl)- and 1-(dichloromethyl)silatranes was developed based on the reactions of 1-chlorosilatrane with the binary P(NMe2)3–СHX3 system (X3 = HBrCl, Cl3).

About the authors

N. F. Lazareva

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: nataly_lazareva@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

I. M. Lazarev

A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: nataly_lazareva@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033

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