Homogeneous catalytic systems for the oxidative functionalization of alkanes: design, oxidants, and mechanisms
- Authors: Chepaikin E.G.1, Menchikova G.N.1, Pomogailo S.I.1
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Affiliations:
- A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences
- Issue: Vol 68, No 8 (2019)
- Pages: 1465-1477
- Section: Review
- URL: https://journal-vniispk.ru/1066-5285/article/view/243442
- DOI: https://doi.org/10.1007/s11172-019-2581-5
- ID: 243442
Cite item
Abstract
The best examples of catalysts and catalytic systems for the oxidative functionalization of alkanes and mechanisms of their action are considered. The prospects for industrial application of homogeneous catalysis in the synthesis of key petrochemical products, diff erent oxygenated organic compounds based on natural and associated petroleum gases, are outlined. Special attention is given to transformations of methane.
About the authors
E. G. Chepaikin
A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences
Author for correspondence.
Email: echep@ism.ac.ru
Russian Federation, 8 ul. Akad. Osip’yana, Chernogolovka, Moscow Region, 142432
G. N. Menchikova
A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences
Email: echep@ism.ac.ru
Russian Federation, 8 ul. Akad. Osip’yana, Chernogolovka, Moscow Region, 142432
S. I. Pomogailo
A. G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences
Email: echep@ism.ac.ru
Russian Federation, 8 ul. Akad. Osip’yana, Chernogolovka, Moscow Region, 142432
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