Email this article Crystal structure and two-level supramolecular organization of glycinium triiodide
- Authors: Shestimerova T.A.1, Bykov M.A.1, Wei Z.2, Dikarev E.V.2, Shevelkov A.V.1
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Affiliations:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Department of Chemistry, University at Albany
- Issue: Vol 68, No 8 (2019)
- Pages: 1520-1524
- Section: Full Article
- URL: https://journal-vniispk.ru/1066-5285/article/view/243447
- DOI: https://doi.org/10.1007/s11172-019-2586-0
- ID: 243447
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Abstract
Glycinium triiodide was synthesized and its crystal structure was determined. The crystal structure consists of alternating asymmetric triiodide anions characterized by Raman spectroscopy and glycinium cations. The cations and anions form dimers (GlyH)2(I3)2via (N)H···O, (N)H···I, and (O)H···I hydrogen bonds. The dimers are further linked into chains by secondary I···I interactions between adjacent triiodide anions. The supramolecular structure of glycinium triiodide is discussed in comparison with polyiodides of various cations.
About the authors
T. A. Shestimerova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: shev@inorg.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
M. A. Bykov
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: shev@inorg.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
Z. Wei
Department of Chemistry, University at Albany
Email: shev@inorg.chem.msu.ru
United States, Albany, New York, 12222
E. V. Dikarev
Department of Chemistry, University at Albany
Author for correspondence.
Email: edikarev@albany.edu
United States, Albany, New York, 12222
A. V. Shevelkov
Department of Chemistry, M. V. Lomonosov Moscow State University
Author for correspondence.
Email: shev@inorg.chem.msu.ru
Russian Federation, Build. 3, 1 Leninskie Gory, Moscow, 119991
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