Email this article First example of [6π+2π] cycloaddition of 1,2-dienes to 1,3,5,7-cyclooctatetraene catalyzed by CoI compounds
- Authors: D’yakonov V.A.1, Kadikova G.N.1, Gazizullina G.F.1, Dzhemilev U.M.1
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Affiliations:
- Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
- Issue: Vol 65, No 1 (2016)
- Pages: 200-202
- Section: Full Articles
- URL: https://journal-vniispk.ru/1066-5285/article/view/236899
- DOI: https://doi.org/10.1007/s11172-016-1284-4
- ID: 236899
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Abstract
A stereoselective [6π+2π] cycloaddition of 1,2-dienes to 1,3,5,7-cyclooctatetraene in the presence of a multi-component catalytic system CoI2/dppe/Zn/ZnI2, which led to the formation of substituted (E)-bicyclo[4.2.2]deca-2,4,7-trienes in 76—87% yields, was accomplished for the first time.
About the authors
V. A. D’yakonov
Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
Author for correspondence.
Email: DyakonovVA@gmail.com
Russian Federation, 141 prosp. Oktyabrya, Ufa, 450075
G. N. Kadikova
Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
Email: DyakonovVA@gmail.com
Russian Federation, 141 prosp. Oktyabrya, Ufa, 450075
G. F. Gazizullina
Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
Email: DyakonovVA@gmail.com
Russian Federation, 141 prosp. Oktyabrya, Ufa, 450075
U. M. Dzhemilev
Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
Email: DyakonovVA@gmail.com
Russian Federation, 141 prosp. Oktyabrya, Ufa, 450075
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