Enviar artigo por via de e-mail Synthesis of N-methyl-N-(silylmethyl)amines
- Autores: Gostevskii B.A.1, Lazareva N.F.1
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Afiliações:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Edição: Volume 68, Nº 8 (2019)
- Páginas: 1555-1557
- Seção: Full Article
- URL: https://journal-vniispk.ru/1066-5285/article/view/243452
- DOI: https://doi.org/10.1007/s11172-019-2591-3
- ID: 243452
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Resumo
(Chloromethyl)silanes ClCH2SiMen(OMe)3-n (n = 0—2) react with methylamine at room temperature to give a mixture of secondary N-methyl-N-(silylmethyl)amines MeNHCH2SiMen(OMe)3-n and tertiary N-methy1-N, N-bis(silylmethyl)amines MeN[CH2SiMen(OMe)3-n]2 (n = 0—2). The product ratio depends on the ratio of the starting reactants. At the methylamine : silane ratio of 5 : 1, the main products are tertiary amines, while the increase in the proportion of methylamine (methylamine : silane = 25 : 1) leads to predomination of the secondary amines.
Sobre autores
B. Gostevskii
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: nataly_lazareva@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
N. Lazareva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: nataly_lazareva@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
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