电邮这篇文章 Synthesis of N-methyl-N-(silylmethyl)amines
- 作者: Gostevskii B.A.1, Lazareva N.F.1
-
隶属关系:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- 期: 卷 68, 编号 8 (2019)
- 页面: 1555-1557
- 栏目: Full Article
- URL: https://journal-vniispk.ru/1066-5285/article/view/243452
- DOI: https://doi.org/10.1007/s11172-019-2591-3
- ID: 243452
如何引用文章
开放存取
##reader.subscriptionAccessGranted##
订阅存取
详细
(Chloromethyl)silanes ClCH2SiMen(OMe)3-n (n = 0—2) react with methylamine at room temperature to give a mixture of secondary N-methyl-N-(silylmethyl)amines MeNHCH2SiMen(OMe)3-n and tertiary N-methy1-N, N-bis(silylmethyl)amines MeN[CH2SiMen(OMe)3-n]2 (n = 0—2). The product ratio depends on the ratio of the starting reactants. At the methylamine : silane ratio of 5 : 1, the main products are tertiary amines, while the increase in the proportion of methylamine (methylamine : silane = 25 : 1) leads to predomination of the secondary amines.
作者简介
B. Gostevskii
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: nataly_lazareva@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033
N. Lazareva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: nataly_lazareva@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033
补充文件
